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Geosmin in Perfumery | Première Peau

Q: Is Geosmin natural or synthetic?

. Extraction: Geosmin is not extracted from a natural source for commercial use. It is produced by chemical synthesis — the first total synthesis of racemic geosmin was reported by Marshall and Hochstetler in 1968 (J. Org. Chem., 33, 2593). The molecule has three stereocentres, making enantioselective synthesis non-trivial. Commercial (±)-geosmin (CAS 16423-19-1) is available from fine chemical suppliers; the natural (−)-enantiomer (CAS 19700-21-1) commands a premium. Biosynthetically, geosmin is produced from farnesyl diphosphate (FPP) by a bifunctional sesquiterpene synthase: the N-terminal domain cyclises FPP to germacradienol, which the C-terminal domain converts to geosmin via a retro-Prins fragmentation that releases acetone as a byproduct. Heterologous biosynthesis in Saccharomyces cerevisiae is under active investigation as a production route..

NATURAL AND SYNTHETIC, POPULAR AND WEIRD / earthy · woody · fresh

Geosmin

Category	NATURAL AND SYNTHETIC, POPULAR AND WEIRD
Subcategory	earthy · woody · fresh
Origin
Volatility	Heart-to-Top Note
Botanical	N/A — produced by Streptomyces bacteria and cyanobacteria in soil
Appearance	colorless to pale yellow clear liquid
Odor Strength	High
Producing Countries	N/A — synthetic (manufactured globally)
Pyramid	Heart

The smell of rain hitting dry earth — raw, mineral, almost electrical. Geosmin is a sesquiterpene alcohol produced by soil bacteria, detectable by the human nose at 5 parts per trillion. You have smelled it your entire life without knowing its name.

Scent
Terroir & Origins
The Full Story
Fun Fact
Extraction & Chemistry
In Perfumery
See Also

Scent

At full concentration, geosmin is aggressively earthy — damp cellar, freshly turned clay, sliced raw beetroot. There is a mineral coldness to it, like wet limestone. None of the warmth of patchouli, none of the sweetness of vetiver's earthy facet. Geosmin is drier, sharper, more geological than botanical. It has a faintly metallic quality, the way cold tap water tastes different from bottled.

At extreme dilution — 0.01% or below — it transforms entirely. The harshness vanishes. What remains is a transparent, rain-washed freshness that reads as natural and alive. This is the concentration range used in perfumery: not earth, but the memory of earth after water has touched it.

Evolution over time

Immediately

After a few hours

After a few days

The Molecule — Manufacturers & Variants

Indicative 2025 wholesale prices.

The Full Story

Geosmin (CAS 19700-21-1, C₁₂H₂₂O, MW 182.30) is a bicyclic sesquiterpene alcohol — specifically, (4S,4aS,8aR)-4,8a-dimethyloctahydronaphthalen-4a(2H)-ol. It is the principal odorant of wet earth. Not an abstraction: the actual molecule your nose detects when rain lands on dry soil, when a beetroot is sliced open, when a Streptomyces colony sporulates in garden compost.

The compound was isolated and named in 1965 by Nancy N. Gerber and Hubert A. Lechevalier at Rutgers University, from cultures of Streptomyces griseus. The name derives from Greek: geō (earth) + osmḗ (smell). Gerber elucidated its structure in 1968 as trans-1,10-dimethyl-trans-9-decalol. Its biosynthesis — from farnesyl diphosphate via germacradienol, through a bifunctional terpene synthase — was not fully resolved until 2007 by Jiang, Cane et al.

Human sensitivity to geosmin is extraordinary. The detection threshold of the natural (−)-enantiomer sits between 5 and 15 parts per trillion — roughly one teaspoon dissolved in 200 Olympic swimming pools. The (+)-enantiomer is approximately 11 times less potent. This hyper-sensitivity is not accidental: geosmin signals the presence of water in soil, which held obvious survival value for early hominids. The olfactory receptor OR11A1 has been identified as the primary detector.

Geosmin is produced by Streptomyces (actinobacteria), several genera of cyanobacteria, and certain fungi including Penicillium species. It is the molecule behind the earthy flavour of beetroot and the muddy taint in catfish raised in pond aquaculture. In water treatment, its presence at concentrations as low as 10 ng/L triggers consumer complaints — a persistent headache for municipal utilities worldwide.

Did You Know?

Did you know?

The human nose detects geosmin at 5 parts per trillion — roughly 1,000 times more sensitively than a shark detects blood. This extreme sensitivity is likely an evolutionary adaptation: Streptomyces bacteria produce geosmin most actively in moist soil, so the molecule effectively signals the presence of water. Camels in the Sahara can reportedly smell rain from 80 km away, possibly guided by geosmin carried on wind currents.

Extraction & Chemistry

Extraction method: Geosmin is not extracted from a natural source for commercial use. It is produced by chemical synthesis — the first total synthesis of racemic geosmin was reported by Marshall and Hochstetler in 1968 (J. Org. Chem., 33, 2593). The molecule has three stereocentres, making enantioselective synthesis non-trivial. Commercial (±)-geosmin (CAS 16423-19-1) is available from fine chemical suppliers; the natural (−)-enantiomer (CAS 19700-21-1) commands a premium. Biosynthetically, geosmin is produced from farnesyl diphosphate (FPP) by a bifunctional sesquiterpene synthase: the N-terminal domain cyclises FPP to germacradienol, which the C-terminal domain converts to geosmin via a retro-Prins fragmentation that releases acetone as a byproduct. Heterologous biosynthesis in Saccharomyces cerevisiae is under active investigation as a production route.

↑ See Terroir & Origins for origin-specific methods.

Molecular Formula	C12H22O
CAS Number	19700-21-1
Botanical Name	N/A — produced by Streptomyces bacteria and cyanobacteria in soil
IFRA Status	No known restrictions
Synonyms	TRANS-1,10-DIMETHYL-TRANS-9-DECALOL · PETRICHOR MOLECULE · EARTH SMELL
Physical Properties
Odor Strength	High
Lasting Power	68 hours at 100.00%
Appearance	colorless to pale yellow clear liquid
Boiling Point	251.00 to 252.00 °C. @ 760.00 mm Hg
Flash Point	> 212.00 °F. TCC ( > 100.00 °C. )
Specific Gravity	1.01800 to 1.02300 @ 25.00 °C.
Melting Point	78.00 to 82.00 °C. @ 760.00 mm Hg

In Perfumery

Geosmin functions as a naturalising agent and earthy modifier, used at vanishingly low concentrations — typically 0.01% to 0.1% in the concentrate. At these doses it does not smell of earth; it makes other materials smell more real. A trace of geosmin in a vetiver base gives the impression of actual soil clinging to the roots. In a patchouli accord, it pushes the composition from decorative to feral. In an iris or violet-leaf construction, it provides the cold, mineral ground-note that anchors the powdery facets. Functionally, it is a modifier rather than a structural note. It has no fixative power — MW 182, vapour pressure 0.003 mmHg at 25°C — and evaporates faster than most base-note materials. Its power lies entirely in the human nose's absurd sensitivity to it: a few parts per trillion are enough to register. Geosmin is sold commercially as a 1% dilution in triethyl citrate (TEC), dipropylene glycol (DPG), or ethanol. Organica Aromatics is a notable supplier. It appears in niche compositions that aim for a soil, rain, or forest-floor effect. No current Première Peau fragrance features geosmin, though its mineral-earth character has natural affinity with the asphalt-and-rain architecture of Gravitas Capitale (/products/gravitas-capitale-neo-cologne-citron-asphalt-perfume).

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