Bitter Orange

Dry, bitter, and aromatic — the adult version of orange. Bigarade is the peel of the Seville orange, tart and tannic where sweet orange is juicy and bright.
Scent
The Full Story
Did You Know?
A single bitter orange tree produces three distinct perfumery materials from three different plant organs: bigarade (peel), neroli (flowers), and petitgrain (leaves).
Extraction & Chemistry
Extraction method
Cold pressing of the peel of Citrus aurantium var. amara (bitter/Seville orange). The same tree also produces neroli (steam distillation of flowers) and petitgrain (steam distillation of leaves and twigs). Major producers: Tunisia, Morocco, southern Italy, Spain. The oil has moderate shelf stability but is sensitive to oxidation.
- Formula
- Complex mixture — key component: limonene (C₁₀H₁₆, 90–95%)
- CAS
- 68916-04-1
- Botanical
- Citrus aurantium
- Appearance
- Yellow to golden mobile liquid
- Odour strength
- High
- Lasting power
- 2-4 hours
- Synonyms
- SEVILLE ORANGE SOUR ORANGE BIGARADE
Restricted — contains furanocoumarins (bergaptene); IFRA limits use in leave-on products due to phototoxicity. Bergaptene-free (rectified) grades are available without restriction.
- Flash point
- 118.00 °F. TCC ( 47.78 °C. )
- Specific gravity
- 0.84500 to 0.85100 @ 25.00 °C.
- Refractive index
- 1.46900 to 1.47800 @ 20.00 °C.
In Perfumery
Bitter orange (bigarade) is a top note with more structure and bitterness than sweet orange. It is the peel oil from the same tree (Citrus aurantium) that produces neroli (from flowers) and petitgrain (from leaves) — making this single species the source of three of perfumery's most important materials. Bigarade provides an adult, austere citrus character in classic eaux de cologne, chypres, and aromatic-fougère constructions. It pairs naturally with neroli, petitgrain, lavender, and aromatic herbs.