Coal Tar

PHARMACEUTICALS & CHEMICAL SYNTHESISindustrial by-product · coal-derived · chemical feedstock
BasePyramid
—Strength
—Tenacity
—Origins
Specimen
Coal Tar perfume ingredient
Base
Definition

Coal tar is a viscous dark liquid that is a by-product of deriving coke and coal gas from coal. Naphthalene is its most abundant single component.

EARTHY SMOKY SWEET WARM DRY RESINOUS
crude coal tar, liquor carbonis detergens, liquor picis carbonis, tarcoal
Type
Ingredient
Olfactive family
Resinous
Subfamily
Smoky resins
Cluster
Classic resins
Source
coal (industrial byproduct)
Chemical class
chemical mixture
Instruments
Pyramid
TTop
HHeart
BBase

Scent

Coal tar has a pungent odor. Naphthalene, a major component of the tar, has a strong odor of coal tar or mothballs, and it can be detected at concentrations as low as 0.08 ppm.

The Full Story

Coal tar is a source of polycyclic aromatic hydrocarbons, including naphthalene, phenanthrene and pyrene. It also yields phenols, among them phenol and cresols, and nitrogen heterocycles such as pyridine, picolines, carbazole and quinolines. The composition of coal tar varies with coal type and processing, but typical coal tar is about 10% naphthalene by weight. Several of these compounds serve as starting materials for dyes, tartrazine among them, and for photographic materials.

The major uses of coal tars are carbon-based electrodes for aluminium processing, wood preservatives, resins for paints and coatings, and as a source of valuable organic compounds. Fractional distillation of coal tar recovered tar for roads, benzole as a motor fuel, creosote as a wood preservative, phenol for plastics and cresols as disinfectants. A creosote rich in naphtha smells of naphtha; with less naphtha it smells more of tar. Some phenolic coal tar derivatives have analgesic properties, among them acetanilide, phenacetin and paracetamol. Although not common, coal tar is used topically for relief from some skin conditions. As of 2011, 30 million tons of coal tar were obtained per year, half of which was processed as a source of chemicals.

The use of coal tar in cosmetic products was forbidden in the European Union by a directive in 2009. The residue from the distillation of high-temperature coal tar is classed as a substance of very high concern by the European Chemicals Agency.

Related: Amberwood · Andiroba · Bakhoor · Balsamic Notes · Benzoin Resinoid · Benzyl Benzoate · Benzyl Salicylate · Birch Tar

Did You Know?

In 1856, William Henry Perkin discovered mauveine, the first commercial synthetic organic dye, while attempting to synthesise quinine. Coal tar was the major source of his raw material. The new purple became so popular that English humourists joked about "mauve measles". Perkin also found ways to make coumarin, one of the first synthetic raw materials of perfume.

Extraction & Chemistry

Extraction method

Coal tar is produced by thermal destruction of coal (pyrolysis or carbonization), usually with the objective of obtaining coke. Its composition varies with the process and the type of coal used: lignite, bituminous or anthracite. Most commonly, bituminous coal is used. The tar is further processed, generating fractions of various applications. Distillation of coal tar yields an oil containing about 50% naphthalene, along with twelve other aromatic compounds. The oil is washed with aqueous sodium hydroxide to remove acidic components, chiefly various phenols, and with sulfuric acid to remove basic components, then fractionally distilled to isolate naphthalene.

Formula
Complex natural mixture (key constituents: naphthalene C₁₀H₈; phenol; cresols; pyridine)
CAS
8007-45-2
Appearance
black or dark brown liquid or high-viscosity semi-solid
Synonyms
crude coal tar, liquor carbonis detergens, liquor picis carbonis, tarcoal
IFRA status
See note

No IFRA Standard for the material itself (51st Amendment)

Physical properties
Boiling point
105–355 °C
Flash point
125 °C

In Perfumery

In soaps, tars from pine and coal, which have an odour as phenolic and smoky as that of birch bark tar, are more commonly used than birch tar as a medicating agent.

Role in the formula
01medicating agent
Available as
standard form

See Also

8 notes