Coal Tar

Coal tar is a viscous dark liquid that is a by-product of deriving coke and coal gas from coal. Naphthalene is its most abundant single component.
- Type
- Ingredient
- Olfactive family
- Resinous
- Subfamily
- Smoky resins
- Cluster
- Classic resins
- Source
- coal (industrial byproduct)
- Chemical class
- chemical mixture
Scent
The Full Story
Did You Know?
In 1856, William Henry Perkin discovered mauveine, the first commercial synthetic organic dye, while attempting to synthesise quinine. Coal tar was the major source of his raw material. The new purple became so popular that English humourists joked about "mauve measles". Perkin also found ways to make coumarin, one of the first synthetic raw materials of perfume.
Extraction & Chemistry
Extraction method
Coal tar is produced by thermal destruction of coal (pyrolysis or carbonization), usually with the objective of obtaining coke. Its composition varies with the process and the type of coal used: lignite, bituminous or anthracite. Most commonly, bituminous coal is used. The tar is further processed, generating fractions of various applications. Distillation of coal tar yields an oil containing about 50% naphthalene, along with twelve other aromatic compounds. The oil is washed with aqueous sodium hydroxide to remove acidic components, chiefly various phenols, and with sulfuric acid to remove basic components, then fractionally distilled to isolate naphthalene.
- Formula
- Complex natural mixture (key constituents: naphthalene C₁₀H₈; phenol; cresols; pyridine)
- CAS
- 8007-45-2
- Appearance
- black or dark brown liquid or high-viscosity semi-solid
- Synonyms
- crude coal tar, liquor carbonis detergens, liquor picis carbonis, tarcoal
No IFRA Standard for the material itself (51st Amendment)
- Boiling point
- 105–355 °C
- Flash point
- 125 °C
In Perfumery
In soaps, tars from pine and coal, which have an odour as phenolic and smoky as that of birch bark tar, are more commonly used than birch tar as a medicating agent.