Jod

AkordPRIRODNO I SINTETIČKO, POPULARNO I NEOBIČNOvodeni · metalan · topao
Bazne notePiramida
—Jačina
—Trajnost
3Poreklo
Uzorak
Jod kao sirovina za parfeme
Bazne note
Fantazijska nota / mirisni koncept
Definicija

Iodine is a chemical element with symbol I and atomic number 53. Elemental iodine has a sharp, characteristic odour.

VODENI OZONSKI TOPAO METALAN MINERALAN SLAN MORSKI
Molecular iodine
Type
Sirovina
Olfactive family
Vodeni
Source
Caliche and brines
Chemical class
Halogen
Instrumenti
Piramida
GGornje note
SSrednje note
BBazne note
Zemlje proizvođači
Čile Japan Sjedinjene Američke Države

Miris

Iodine has a sharp, characteristic odour. Another description of the odour of iodine is irritating. At very high concentrations, bromophenols give a harsh chemical smell similar to iodine.

Detaljno

Iodine is the heaviest of the stable halogens. At standard conditions it is a semi-lustrous, non-metallic solid that melts into a deep violet liquid. Of the stable halogens, iodine is the least volatile, yet the solid can still be seen giving off purple vapour. Iodine is the least abundant of the stable halogens, at only 0.46 parts per million of Earth's crustal rocks. Iodine vapour is very irritating to the eyes, the mucous membranes and the respiratory tract. Only one stable isotope, iodine-127, is found in nature.

Seaweed washed onto the shore was called varec in French, and the word later also referred to the ashes of such seaweed. Those ashes were used as a source of iodine and salts of sodium and potassium. Kelp stores large quantities of iodide, primarily as iodotyrosines, for unknown reasons. Natural sources of iodine include many marine organisms, such as kelp and certain seafood products.

No single chemical compound can really be pinned down as the essence of the ocean. A diverse mix of molecules contributes to the smell of the seashore. Dimethyl sulfide is one of the most common and best-understood components of seashore aroma. The brininess of wild seafood comes in large part from a class of compounds called bromophenols. In low concentrations, these chemicals are described as smelling sealike, fishlike and crablike. Some farmers have tried adding bromophenols to the diets of farm-raised seafood to re-create the flavour of ocean-faring fish, with mixed success. One challenge is striking a balance between a hint of ocean flavour and the overbearing metallic tang of iodine. One organoiodine, 1-iodopentane, was identified at 0.8% in the headspace volatiles of the alga Halopteris filicina from the Adriatic Sea.

Iodine is required for the synthesis of thyroid hormones. It also serves as a catalyst in the industrial production of acetic acid and some polymers. Tincture of iodine is an antiseptic that contains iodine, ethanol and water. It is usually 2% elemental iodine, with potassium iodide or sodium iodide, dissolved in ethanol and water. Povidone-iodine is an antiseptic used for skin disinfection before and after surgery. It is a chemical complex of povidone, hydrogen iodide and elemental iodine. It is sold under a number of brand names including Betadine.

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Related: Aqual · Aquozone · Calone · Calone 1951 · Coral Limestone · Crustaceans · Diving Suit · Fish

Zanimljivosti

When Bernard Courtois added sulfuric acid to seaweed ash, a cloud of violet vapour arose. Gay-Lussac suggested the name iodine after the Ancient Greek word for 'violet', because of the colour of iodine vapour.

Dobijanje i hemija

Način dobijanja

Sodium iodate is extracted from the caliche and reduced to iodide by sodium bisulfite. The caliche is found in Chile, and its main product is sodium nitrate. This solution is then reacted with freshly extracted iodate, which gives iodine by comproportionation, and the iodine may be filtered off. In the late 20th century brines emerged as a comparable source of iodine. The brine is first purified and acidified with sulfuric acid, then the iodide present is oxidised to iodine with chlorine. An iodine solution is produced, but it is dilute and must be concentrated. Air is blown into the solution to evaporate the iodine, which is passed into an absorbing tower, where sulfur dioxide reduces the iodine. The hydrogen iodide is then reacted with chlorine to precipitate the iodine.

Formula
I₂
CAS
7553-56-2
Sinonimi
Molecular iodine
Status prema standardima IFRA
Pogledajte napomenu

No IFRA Standard for the material itself (51st Amendment)

Fizička svojstva
Tačka ključanja
184 °C
Tačka topljenja
114 °C
Relativna gustina
4.93

U parfemima

Seaweed absolute delivers slightly salty marine notes. It is also used to add subtle hints of hay, smoke and walnut. Calone is used to give the olfactory impression of a fresh seashore through its marine and ozone nuances.

Uloga u formuli
01svežina
02fiksativ
Oblici na tržištu
kristali

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