Heksil-acetat

Prirodna i sintetičkaMIRISNA JEDINJENJAvoćni · zelen · svež
Gornje notePiramida
3/5Jačina
5hTrajnost
—Poreklo
Uzorak
Heksil-acetat kao sirovina za parfeme
Gornje note
Definicija

Hexyl acetate is an ester with the molecular formula C₈H₁₆O₂. Its odor is described as green, fruity, sweet and fresh, with notes of apple and pear.

CVETNI ZELEN SLADAK VOĆNI SVEŽ
acetic acid hexyl ester, hexyl ethanoate, n-hexyl acetate, 1-hexyl acetate, capryl acetate, acetate C-6
Type
Sirovina
Olfactive family
Voćni
Source
found naturally in many fruits
Chemical class
ester
Instrumenti
Piramida
GGornje note
SSrednje note
BBazne note
3/5Jačina
Srednja
jačina mirisa
Trajnost na mirisnoj traci
5sati
1 h6 h24 h3 d7 d400 h
pri 100 %

Miris

The odor is green, fruity, sweet, fatty and fresh, with apple and pear. It is also described as sweet, fruity, pear-like and somewhat green. Another description calls it a green, fruity, sweet, aldehydic note reminiscent of pear. It resembles amyl acetate but is milder, with floral and green facets. The liquid has a mild sweet odor. Further descriptions add banana and cherry, with floral nuances of magnolia and wisteria.

Detaljno

Chemistry

Hexyl acetate is the acetate ester of hexan-1-ol. It is a metabolite found in or produced by Saccharomyces cerevisiae. It is very soluble in alcohol and ether. Its solubility in water is 511 mg/L at 25 °C. It is less dense than water. Heated to decomposition, it gives off acrid smoke and fumes.

Occurrence in fruit

It is naturally present in many fruits, such as apples and plums, as well as in alcoholic beverages. Butyl acetate, hexyl acetate, 2-methylbutyl acetate and ethyl 2-methylbutanoate are the most important esters for the aroma of several apple varieties, because of their high content and impact. Hexyl acetate, 2-methylbutyl acetate and ethyl 2-methylbutanoate contribute mostly to the characteristic aroma of Fuji apples. In pears, hexyl acetate is one of several volatile esters that possess strong pear-like aromas. Hexyl acetate is one of the esters considered key odorants influencing the flavor quality of peach fruit. It is one of six major volatiles identified in Modesto apricots. It has also been detected in apricots, plums and nectarines.

Uses

Hexyl acetate is mainly used as a solvent for resins, polymers, fats and oils. It is also added to paint to improve dispersion on a surface. It is also used as a propellant in aerosols.

Environmental behavior

In air, the vapor is broken down by reaction with hydroxyl radicals produced by sunlight chemistry, with an estimated half-life of 2.2 days. It is expected to volatilize from dry soil surfaces.

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Related: Acerola · Akebia Fruit · Allyl Amyl Glycolate · Arctic Bramble · Argan · Berries · Black Sapote · Buriti

Dobijanje i hemija

Način dobijanja

A direct esterification of n-hexanol with acetic acid at 115 °C for 70 minutes, at a hexanol to acetic acid ratio of 1.2 and with benzene to carry off the water, gave a yield of 96.36%. A solid superacid catalyst, S₂O₈²⁻/TiO₂, has also been used, and at 100 to 110 °C for 2 hours it gave an esterification conversion above 96%. The enzymatic route uses immobilized lipase from Mucor miehei to catalyze the transesterification of hexanol with triacetin.

Formula
C₈H₁₆O₂
CAS
142-92-7
Izgled
colorless clear oily liquid
Jačina mirisa
Srednji
Trajnost
5 hours at 100.00%
Sinonimi
acetic acid hexyl ester, hexyl ethanoate, n-hexyl acetate, 1-hexyl acetate, capryl acetate, acetate C-6
Status prema standardima IFRA
Pogledajte napomenu

No IFRA Standard for the material itself (51st Amendment)

Fizička svojstva
Tačka ključanja
170.00 to 172.00 °C. @ 760.00 mm Hg
Tačka topljenja
-80.00 °C. @ 760.00 mm Hg
Tačka paljenja
132.00 °F. TCC ( 55.56 °C. )
Relativna gustina
0.86800 to 0.87600 @ 25.00 °C.
Indeks prelamanja
1.40600 to 1.41100 @ 20.00 °C.

U parfemima

Hexyl acetate is used as a flavoring because of its fruity odor. Its FEMA number is 2565 and its JECFA number is 128. It is listed in the Food Chemicals Codex. Smelling it in a solution of 10 % or less is recommended.

Uloga u formuli
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