Liči (lychee)

PrirodnaVOĆE, POVRĆE I ORAŠASTI PLODOVIvoćni · cvetni · ružin
Gornje notePiramida
—Jačina
—Trajnost
5Poreklo
Uzorak
Liči (lychee) kao sirovina za parfeme
Gornje note
Litchi chinensis
Definicija

Lychee is the fruit of the tree Litchi chinensis, the sole member of the genus Litchi, in the soapberry family Sapindaceae. Its flavor is sweet and mildly tart, with a distinctive floral aroma often described as rose-like.

CVETNI SLADAK VOĆNI KAO RUŽA
Litchi
Type
Sirovina
Olfactive family
Voćni
Source
Fruit of Litchi chinensis
Instrumenti
Piramida
GGornje note
SSrednje note
BBazne note
Zemlje proizvođači
Kina Indija Madagaskar Tajland Vijetnam

Miris

Lychee has a distinctive flavor and is usually described as rose-floral and fruity-floral in aroma. Among the aroma attributes of the 'Sweetheart' cultivar, floral was the most intense, followed by tropical fruit, peach/apricot and honey. By contrast, the lychee samples showed relatively low odor intensities for citrus, cabbage, green/woody and garlic/onion.

Methional is perceived as cooked potato, and geraniol as sweet and floral. Geraniol has a rose-like scent. Nerol is floral and sweet, linalool is floral, dimethyl trisulfide is pickled vegetable and sulfury, and nerolidol is metallic, sesame oil. The (+)-cis-rose oxide is perceived as green and floral. In Muscaris and Muskateller grapes, the (2S,4R) enantiomer of cis-rose oxide smells floral and lychee-like (strong), while the (2R,4S) enantiomer is floral and lychee-like only weakly.

Detaljno

Lychee — crystalline, transparent, faintly rose-adjacent — is used in PREMIEREPEAU's Rose Monotone to refract rose oxide and Brazilian pink pepper.

Lychee is a member of the Sapindaceae family, which also includes longan and rambutan. There are three distinct subspecies of lychee. Litchi chinensis subsp. chinensis is the only commercialized lychee, and it grows wild in southern China, northern Vietnam, and Cambodia.

The outside of the fruit is a pink-red, rough-textured soft shell. The edible aril is juicy and translucent. At full maturity the flesh is a white, juicy aril surrounding a large brown seed. The seeds contain methylene cyclopropyl glycine, which has caused hypoglycemia linked to outbreaks of encephalopathy in undernourished Indian and Vietnamese children who ate the fruit. Lychee's sweetness is primarily due to sucrose, glucose, and fructose, while malic and citric acids provide acidity.

Aroma-active compounds in the flesh include the monoterpenes linalool, geraniol, nerol, limonene, and cis-rose oxide, which contribute rose-like and citrus-like notes. The flesh also contains furaneol, methional and sulfur volatiles such as dimethyl trisulfide.

In the 'Sweetheart' cultivar, methional and geraniol showed the highest flavor dilution factors, 1024 and 512 respectively. Geraniol, nerol and linalool are the most aroma-active terpenes due to their low sensory threshold. The strong combination of these three volatiles explained the most intense floral note of lychee fruit perceived in the sensory evaluation. Besides giving the impression of a floral note, linalool can also contribute sweet and citrus scents to the overall aroma profile of lychee.

Rose oxide is an organic compound of the pyran class of monoterpenes. Rose oxide also contributes to the flavor of some fruits, such as lychee. Only the (-)-cis isomer of rose oxide, with an odor threshold of 0.5 ppb, is responsible for the typical rose (floral green) fragrance.

A comparison of Gewürztraminer wine, fresh lychees and canned lychees detected 12 odorants common to all three samples. Among them, cis-rose oxide, β-damascenone, ethyl 2-methylpropanoate, linalool and geraniol consistently showed concentrations beyond their odor threshold concentrations. Together with geraniol, nerol and citronellol, linalool is one of the rose alcohols.

The aroma-active compounds of 'Sweetheart' lychee were isolated with solvent assisted flavor evaporation and examined by gas chromatography-olfactometry/mass spectrometry. The most important odorants were then characterized by aroma extract dilution analysis. Thirty-one key aroma-active odorants were identified, with flavor dilution factors from 2 to 1024.

In the distilled spirit, linalool, cis-rose oxide and trans-rose oxide had the highest odor activity values, which may explain its rose and flower aroma. Some yeast strains can metabolize geraniol into cis-rose oxide.

In the PREMIEREPEAU collection, lychee appears in Rose Monotone, where its crystalline fruitiness amplifies the cooler, mineral quality of the rose accord.

Related Notes

This note in PREMIEREPEAU. Rose Monotone. Sample all seven extraits in the Discovery Set.

Zanimljivosti

Gewürztraminer wines have a flamboyant bouquet of lychees, and the grape and lychees share the same aroma compounds. Since the floral flavor is lost in the process of canning, the fruit is usually eaten fresh.

Dobijanje i hemija

Način dobijanja

Rose oxide, which contributes to the flavor of lychee, can be produced industrially beginning with photooxygenation of citronellol to give the allyl hydroperoxide which is then reduced with sodium sulfite to provide the diol. Ring-closure with sulfuric acid forms both the cis- and trans-isomers in equal amounts.

CAS
876-17-5 ((+)-cis-rose oxide) · 78-70-6 (linalool)
Botanički naziv
Litchi chinensis
Sinonimi
Litchi
Status prema standardima IFRA
Pogledajte napomenu

No IFRA Standard for the material itself (51st Amendment)

U parfemima

Rose oxide is a fragrance chemical found in roses and rose oil. Odor reconstitution and omission experiments showed that the distinct lychee note in the aroma of the Muscaris grapes was generated by the combination of (2S,4R)-rose oxide and geraniol. (2S,4R)-rose oxide was the only compound among the odorants identified in Muscaris and Muskateller grapes with a specific lychee-like odor. Linalool, one of the aroma-active compounds of lychee flesh, is used as a scent in perfumed hygiene products and cleaning agents, including soaps, detergents, shampoos, and lotions. Featured in PREMIEREPEAU's Rose Monotone (/products/rose-monotone-crystalline-lychee-perfume), where it anchors the crystalline-fruity quality of the composition alongside a mineral rose accord.

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