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НатуральнийДЕРЕВИНА Й МОХИсвіжий · деревний · землистий

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Pinus sylvestris
Визначення

Pine tree, in perfumery, is pine needle oil: the oil from the needles of Pinus sylvestris. Its odour is described as earthy, dry, weedy, green, pine and woody.

Boisé
91
Terreux
63
Vert
60
Fumé
50
Résineux
38
Doux
35
Pine needle oil, Pinus sylvestris needle oil
Type
Складник
Olfactive family
Деревні
Source
needles
Chemical class
complex natural (essential oil)
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
Країни-виробники
Азія Європа Північна Америка

Запах

The odour of Pinus sylvestris needle oil is described as earthy, dry, weedy, green, pine and woody. Its principal odour type is earthy.

Теруар і зрілість

Докладно

Pine needle oil is the oil from the needles of Pinus sylvestris. Pinus sylvestris is a species of conifer, a pine, in the family Pinaceae, and it is native to Eurasia. In English it is known as the Scots pine. The tree can readily be identified by its fairly short, blue-green leaves and orange-red bark. It is the only pine native to northern Europe, ranging from Western Europe to Eastern Siberia.

Composition

Essential oils from different parts of Pinus species have complex chemical compositions. Across all species examined, α-pinene is the most consistently dominant compound in both needles and cones. Essential oils from needles tend to be more complex and diverse, frequently containing limonene, β-pinene, δ-3-carene and bornyl acetate. Essential oils from cones show higher relative abundances of caryophyllene oxide, aromadendrene and abietane-type diterpenes. The oils of P. sylvestris and P. peuce are characterized by a high content of α-pinene, exceeding 40%.

Turpentine and Terpene Chemistry

Turpentine is a fluid obtainable by the distillation of resin harvested from living trees, mainly pines. It is principally used as a specialized solvent and is also a source of material for organic syntheses. Turpentine is composed of terpenes, primarily the monoterpenes α-pinene and β-pinene, with lesser amounts of carene, camphene, limonene and terpinolene. Important pines for turpentine production include maritime pine (Pinus pinaster), Aleppo pine (Pinus halepensis), Masson's pine (Pinus massoniana), Sumatran pine (Pinus merkusii) and longleaf pine (Pinus palustris). The mixture of diterpenes and triterpenes that is left as residue after turpentine distillation is sold as rosin. α-Pinene is an organic compound of the terpene class. It is found in the oils of many species of coniferous trees, notably Pinus and Picea species. In nature the (-)-enantiomer of α-pinene is more common in European pines, whereas the (+)-isomer is more common in North America.

Pine Oil in the Commercial Sense

Pine oil in the commercial sense is a higher boiling fraction from turpentine. Both synthetic and natural pine oil consist mainly of α-terpineol, a C10 alcohol. Synthetic pine oils accounted for 90% of sales as of 2000. Pine oil is used as a cleaning product, disinfectant, sanitizer, microbicide, virucide or insecticide. Industrially, pine oil was once used in froth flotation for the separation of mineral from ores. In alternative medicine it is used in aromatherapy and as a scent in bath oils. The naval stores industry produces and markets products derived from the oleoresin of pine trees, including rosin, tall oil, pine oil and turpentine.

Цікавий факт

The tallest Scots pine on record, a tree over 210 years old, grows in Estonia and stands 46.6 m tall. The oldest recorded specimens, in Lapland in northern Finland, are over 760 years old. The lifespan of the tree is normally 150 to 300 years, and its needles stay on the tree for two to four years in warmer climates and up to nine years in subarctic regions.

Отримання й хімія

Спосіб отримання

Essential oil from the needles of Pinus sylvestris has been obtained by hydro-distillation. Crude turpentine collected from the trees may be evaporated by steam distillation in a copper still. Molten rosin remains in the still bottoms after turpentine has been distilled out. Nowadays, turpentine is rarely the product of distillation of pine resin, but is a byproduct of pulping. Pine oil in the commercial sense is typically made by grinding parts of the trees that are not used for lumber, such as stumps, and subjecting them to steam distillation. Synthetic pine oil is obtained by treating pinene with water in the presence of a catalytic amount of sulfuric acid. This treatment results in hydration of the alkene and rearrangement of the pinene skeleton, yielding terpineols.

Формула
Complex natural mixture (key constituents: alpha-pinene C₁₀H₁₆)
CAS
8023-99-2
Ботанічна назва
Pinus sylvestris
Зовнішній вигляд
Colorless to pale yellow clear liquid
Синоніми
Pine needle oil, Pinus sylvestris needle oil
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Відносна густина
0.85700 to 0.88500 @ 25.00 °C.
Показник заломлення
1.47300 to 1.47850 @ 20.00 °C.

У парфумерії

Turpentine is also used as a source of raw materials in the synthesis of fragrant chemical compounds. Camphor, linalool, alpha-terpineol and geraniol are all usually produced from alpha-pinene and beta-pinene, which are two of the chief chemical components of turpentine. 2-Pinanol, derived from pinene, gives linalool upon pyrolysis. Turpentine is also added to many cleaning and sanitary products because of its antiseptic properties and its clean scent. Turpentine has also been exploited for uses in fragrances, flavors, vitamins, household cleaning products, medicines and polyterpene resin.

Роль у формулі
01модифікатор
02кістяк
03фірмова нота
04компонент піднесення
05сполучний компонент
06формувач об’єму
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ефірна олія

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