Троянда

НатуральнийКВІТИквітковий · медовий · зелений
Ноти серцяПіраміда
3½/5Сила
5годСтійкість
4Походження
Зразок
Троянда як парфумерна сировина
Ноти серця
Rosa damascena Rosa centifolia
Визначення

Bulgarian rose oil has an intense, warm, deep floral, waxy odour, slightly spicy and very rich, with traces of honey.

Floral
100
Vert
82
Doux
75
Poudré
42
Fruité
30
Boisé
24
rose oil, rose otto, attar of roses, otto of roses, rose essence
Type
Складник
Olfactive family
Квіткові
Source
flowers
Chemical class
complex natural (essential oil)
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
3½/5Сила
Вище середньої
інтенсивність запаху
Стійкість на блотері
5годин
1 год6 год24 год3 дн.7 дн.400 год
Країни-виробники
Болгарія Франція (Грас) Марокко Туреччина

Запах

Bulgarian rose oil finishes with a rosy-aldehydic dry-out lasting about 5 days. Rose attar has a very strong odour, but it is pleasant when diluted and used for perfume. Rose oil does not reflect the true scent of rose flowers, since certain aroma components, particularly phenylethyl alcohol, are partially lost during distillation. Phenethyl alcohol, a component of rose oil, has a pleasant floral odour, soft and like roses. The aroma of beta-damascenone is described as apple, rose, honey, tobacco and sweet. Rosa × centifolia is cultivated for its fragrance, clear and sweet with light notes of honey.

Теруар і походження

Докладно

Rose is the most documented material in perfumery — reframed in PREMIEREPEAU's Rose Monotone, where rose oxide locks into Brazilian pink pepper, lychee, and Haitian vetiver.

Two major species of rose are cultivated for the production of rose oil, Rosa damascena and Rosa centifolia. The Damask rose, Rosa × damascena, is a rose hybrid derived from Rosa gallica and Rosa moschata. DNA analysis has shown that a third species, Rosa fedtschenkoana, made some genetic contributions to the Damask rose. Rosa × damascena is a cultivated flower not found in the wild. The Damask rose is a deciduous shrub that grows to a height of 2.2 metres. Rosa × centifolia, the Provence rose, cabbage rose, May rose or Rose de Mai, is a hybrid rose developed by Dutch breeders between the 17th century and the 19th century, possibly earlier. Its parentage includes Rosa × damascena. The flowers of Rosa × centifolia are round and globular, with numerous thin overlapping petals that are highly scented.

Rosa damascena production today is dominated by three producers that account for over 70% of the rose oil market share: Bulgaria, Turkey and Saudi Arabia. Rosa × damascena is optimally cultivated in hedgerows to help protect the blooms from wind damage and facilitate harvesting. In Bulgaria, damask roses are grown in long hedges, while in Turkey, individual plants are spaced apart along trenches. A state cooperative in Turkey's Isparta region carefully regulates the commercialization of rose oil, although families still operate small distilleries. Oil produced in Russia is mainly traded and consumed locally. The bulk of all export is to France, the United States, Switzerland and the United Kingdom. A period of winter dormancy is essential for damask rose to induce bud development. All flower parts contain essential oil, which generally reaches its maximum when the petals become cup-shaped and the stamens bright yellow; the petals contain most oil. The economic life of a plantation is 10–12 years, and flower yield normally increases during the first 5–7 years and then declines gradually. Because production is labour-intensive and the rose blooms hold little oil, rose oil commands a very high price. Some of these oils are up to 90% geranium or palmarosa to 10% rose, a practice called extending the rose fragrance.

About 283 components have been identified in the composition of Bulgarian rose oil. Analysis has revealed more than 300 constituents in rose oil, most in very small proportions but many of them important for the depth of its fragrance. Rose oil contains citronellol (20–34%), geraniol (15–22%) and nonadecane (8–15%) as major components. Damask rose oil contains more than 1% each of citronellol, geraniol, nerol, linalool and phenylethyl alcohol. The ratio of citronellol to geraniol and nerol, the three main terpene alcohols, is of major importance in determining the quality of rose oil. In Bulgarian rose oil, the odour carriers form the liquid part, the eleoptene, while the odour fixatives, the stearoptene, are hard at room temperature and odourless but give the odour durability. Stearoptene is odourless and makes up 15–25% of the oil. When cooled below 20 °C, Bulgarian rose oil precipitates white or colourless crystals of stearoptene, and the remaining liquid is known as elaeoptene. The Rosa centifolia absolute is composed of more than 50% phenylethyl alcohol, and the rest of its composition resembles that of Rosa damascena. Bulgarian distilled rose oil is naturally low in phenylethanol, and Ukrainian or Russian rose oil is naturally high in phenylethanol.

Beta-damascenone makes up 0.01–1.85% of rose oil, and its presence is considered the marker for the quality of the oil. The other key components are beta-damascone, other damascones, beta-ionone and rose oxide, each under 1% of the oil. These key components usually make up less than 1% of rose oil, yet they account for slightly more than 90% of its odour content because of their low odour detection thresholds. A component's contribution to the overall smell can be assessed in odour units, the concentration of the molecule divided by its odour threshold. Low-abundance but intensely smelly molecules such as beta-damascenone, beta-ionone, beta-damascone and rose oxide contribute most to rose aroma. Beta-damascenone is a major contributor to the aroma of roses despite its very low concentration. Damascenone takes its name from Rosa damascena. The damascenones belong to the rose ketones, a family of chemicals that also includes damascones and ionones. The damascenones are derived from the degradation of carotenoids. Beta-damascenone cannot be detected in rose petals but is present in rose oil, which means it must form from a precursor compound, possibly by heating. Phenethyl alcohol, or 2-phenylethanol, is an organic compound with the chemical formula C₈H₁₀O. Phenethyl alcohol is found in extracts of rose, carnation, hyacinth, Aleppo pine, orange blossom, ylang-ylang, geranium, neroli and champaca.

Damask rose petals are edible and are used to flavour food, as a garnish, as herbal tea, and preserved in sugar as gulkand. Damask roses are used in cooking as a flavouring ingredient or spice, and they are an ingredient in the spice mixture ras el hanout. Rose water and powdered roses are used in Middle Eastern and Indian cuisine. Rose petals can be crystallized with sugar to make a sweetmeat, and dried petals are added to drinks as a flavouring.

Rose oxide drives the crystalline quality ofRose Monotone, paired with lychee and pink pepper in a deliberate exploration of rose's cooler, mineral side.

This note in PREMIEREPEAU. Nuit Élastique · Rose Monotone. Sample all seven extraits in the Discovery Set.

Цікавий факт

In the rose oil whose composition is tabulated by odour units, beta-damascenone makes up only 0.14% of the oil yet accounts for 70.0% of the relative odour units. Its odour threshold there is 0.009 ppb, against 40 ppb for citronellol, which makes up 38% of that oil. Beta-ionone is just 0.03% of the same oil but carries 19.2% of the relative odour units. Rose attar forms white crystals at normal room temperature, and they disappear when the oil is gently warmed.

Отримання й хімія

Спосіб отримання

Rose ottos are extracted through steam distillation, while rose absolutes are obtained through solvent extraction. Steam distillation produces an essential oil called rose otto or attar of roses. Solvent extraction results in an absolute called rose absolute. Supercritical carbon dioxide extraction yields a concrete that may be marketed as a concrete, absolute or CO₂ extract. Rose oil is produced by a two-stage distillation process because many of the aroma compounds of roses are water-soluble. In the first stage, large stills, traditionally of copper, are filled with roses and water, and the still is fired for 60–105 minutes. The vaporized water and rose oil exit the still, enter a condensing apparatus and are then collected in a flask. This distillation yields a very concentrated oil, the direct oil, which makes up about 20% of the final product of the whole process. The water that condenses with the oil is drained off and redistilled, a step called cohobation, to obtain the water-soluble fractions of the rose oil, such as phenethyl alcohol, which are a vital component of the aroma. These water-soluble fractions make up the large bulk, 80%, of the oil. The two oils are combined and make the final rose attar. Depending on extraction method and plant species, the typical yield can be approximately 1:3,000. Water distillation yields 0.01–0.04% of essential oil. Annual damask rose flower yield averages 1–3.5 t/ha, and 2–4 t of flowers are required to produce 1 kg of oil. Solvent extraction of rose flowers is now frequently used. Rose concrete is obtained by extraction of rose flowers, often with hexane, and rose absolute by extraction of the concrete with alcohol. In Morocco, 1.8 kg of concrete or 0.9 kg of absolute is obtained from 1,000 kg of Rosa centifolia flowers. Like solvent extraction, CO₂ extraction takes place at a low temperature and leaves the aromatics unaltered by heat. It extracts a wide range of compounds, rendering an essence more faithful to the original. Because CO₂ is a gas at normal atmospheric pressure, it leaves no trace of itself in the final product. The equipment for CO₂ extraction is expensive. Harvesting of flowers is done by hand in the morning before sunrise, and the material is distilled the same day. Picking should be done between 5 and 10 a.m., when the flowers open and oil content is highest. Whole, fully open flowers should be selected because they have the highest oil content, not buds or previous day flowers. Whole flowers are picked for rose oil, and young buds are selected for the highest yield of concrete. An experienced worker can pick 3–6 kg per hour. Damask rose flowers should be transported to the distillery without delay.

Формула
Complex natural mixture (key constituents: citronellol; geraniol; nerol; nonadecane; phenylethyl alcohol C₈H₁₀O; beta-damascenone C₁₃H₁₈O)
CAS
8007-01-0
Ботанічна назва
Rosa damascena Rosa centifolia
Зовнішній вигляд
Pale yellow to yellow-green (Bulgarian rose oil)
Сила запаху
Середня (отто) · Від середньої до сильної (абсолют)
Стійкість
Dry-out lasting about 5 days
Синоніми
rose oil, rose otto, attar of roses, otto of roses, rose essence
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

У парфумерії

Rose oils are used in perfumery, and the absolute is used more commonly there than the otto. Even with their high price and the advent of organic synthesis, rose oils are perhaps still the most used essential oil in perfumery. Several formulations to compound synthetic rose fragrances have been published, some modified to match the odour of rose oil of different origins. Phenethyl alcohol, a component of rose oil, is a common ingredient in flavours and perfumery, particularly when the odour of rose is desired. Beta-damascenone is an important fragrance chemical used in perfumery. The flowers of the Damask rose are commercially harvested for rose oil used in perfumery and for making rose water and rose concrete. The flowers of Rosa × centifolia are commercially harvested for the production of rose oil, which is commonly used in perfumery.

Роль у формулі
01підсилювач дифузії
02модифікатор
03фірмова нота
04сполучний компонент
05формувач об’єму
06свіжість
Форми випуску
ефірна олія абсолют конкрет

Див. також

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