Grejpfrut

PrirodnaCITRUSNI MIRISIcitrusni · voćni · svež
Gornje notePiramida
3/5Jačina
—Trajnost
3Poreklo
Uzorak
Grejpfrut kao sirovina za parfeme
Gornje note
Citrus × paradisi
Definicija

Tart, sparkling, faintly sulfurous. Grapefruit smells like sunrise on a terrace — a bright citrus burst with a bitter edge, a juicy sweetness, and an almost metallic tang that no other citrus possesses.

CITRUSNI SLADAK SVEŽ GORAK
pamplemousse, pomelo hybrid
Type
Sirovina
Olfactive family
Citrusni
Source
fruit
Chemical class
complex natural (expressed oil)
Instrumenti
Piramida
GGornje note
SSrednje note
BBazne note
3/5Jačina
Srednja
jačina mirisa
Zemlje proizvođači
Izrael Južnoafrička Republika Sjedinjene Američke Države

Miris

More bitter than orange, less acid than lemon, with a sulfurous-metallic undertone that neither possess. Grapefruit opens with explosive citrus brightness — d-limonene's clean, universally recognizable sparkle — then immediately reveals the nootkatone signature: a bitter, slightly woody, almost grapefruit-rind quality that is drier and more persistent than any other citrus. There is a faint thiol note (mercaptan compounds at trace levels) that adds a sulfurous, almost tropical edge. On blotter, the limonene-dominant top vanishes in under an hour, but nootkatone, being a sesquiterpene, persists noticeably longer than typical citrus notes.

Teroar i oblici

Detaljno

Grapefruit (Citrus × paradisi) is a hybrid of pomelo (Citrus maxima) and sweet orange (C. sinensis), thought to have originated in Barbados in the seventeenth or eighteenth century. The cold-pressed peel oil (CAS 8016-20-4) is the standard perfumery natural; it is limonene-dominant like all citrus, but two minor compounds make grapefruit immediately recognisable.

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The two signature compounds

Nootkatone (CAS 4674-50-4, a sesquiterpene ketone, C₁₅H₂₂O) is the woody-bitter heart of grapefruit [A] — it carries the characteristic grapefruit angle from limonene's plain citrus. Even more important at trace level is 1-p-menthene-8-thiol (CAS 71159-90-5), the powerful sulphur thiol that supplies the metallic-fresh juicy quality, identifiable below ~10 ppb in finished fragrance [B]. Together these two compounds — both at trace levels — turn an otherwise ordinary citrus oil into something only grapefruit smells like.

Sources & Notes

[A] PubChem CID 1268142 — nootkatone, CAS 4674-50-4. The sesquiterpene ketone signature of grapefruit. pubchem.ncbi.nlm.nih.gov/compound/1268142.

[B] PubChem CID 6427135 — 1-p-menthene-8-thiol (grapefruit mercaptan), CAS 71159-90-5. The trace sulphur thiol responsible for grapefruit's metallic juiciness. pubchem.ncbi.nlm.nih.gov/compound/6427135.

Dobijanje i hemija

Način dobijanja

Cold pressing of Citrus x paradisi peel. The oil is 90-95% d-limonene with 0.01-0.8% nootkatone — the sesquiterpene ketone responsible for the characteristic grapefruit identity. Cold-pressed oil contains phototoxic furocoumarins (IFRA-restricted in leave-on products). Distilled grapefruit oil is furocoumarin-free but lacks some peel-fresh character. Nootkatone can be used as an isolate to deliver grapefruit character without phototoxicity restrictions.

Formula
complex mixture (limonene C₁₀H₁₆ ~90%, nootkatone trace)
CAS
8016-20-4
Botanički naziv
Citrus × paradisi
Izgled
pale yellow to yellow clear liquid
Jačina mirisa
Srednji
Sinonimi
pamplemousse, pomelo hybrid
Status prema standardima IFRA
Ograničeno

Restricted (expressed) — phototoxic when expressed; IFRA limits in leave-on products

Fizička svojstva
Tačka ključanja
171.00 °C. @ 760.00 mm Hg
Tačka paljenja
112.00 °F. TCC ( 44.44 °C. )
Relativna gustina
0.86300 to 0.97000 @ 25.00 °C.
Indeks prelamanja
1.47800 to 1.54000 @ 20.00 °C.

U parfemima

Grapefruit functions as a top note with slightly longer tenacity than most citrus materials, thanks to nootkatone's sesquiterpene weight. It provides a bright, bitter-fresh opening for cologne, hesperidic, fresh-spicy, and green-citrus compositions. The bitterness distinguishes it from sweeter citrus notes (orange, mandarin) and makes it a natural partner for green tea, vetiver, pepper, and woody-mineral bases. Grapefruit is prominent in the modern cologne genre, where its clean tartness creates a unisex freshness.

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