Банан

Banana oil is another name for isoamyl acetate, an ester formed from isoamyl alcohol and acetic acid. Its odour is strong and described as similar to both banana and pear.
- Type
- Складник
- Olfactive family
- Фруктові
- Source
- synthetic ester (isoamyl acetate); occurs naturally in banana fruit volatiles
- Chemical class
- ester
Запах
Докладно
Отримання й хімія
Спосіб отримання
Isoamyl acetate is prepared by the acid-catalyzed reaction (Fischer esterification) between isoamyl alcohol and glacial acetic acid. Typically, sulfuric acid is used as the catalyst; p-toluenesulfonic acid or an acidic ion exchange resin can be used instead. The unfavorable equilibrium of a Fischer esterification must be remedied, for example by a large excess of one of the reagents or by removing the water. Isoamyl alcohol is a common fusel alcohol, produced as a major by-product of ethanol fermentation. Isoamyl alcohol can be separated from fusel oil by shaking with strong brine solution and separating the oily layer, or by distilling it and collecting the fraction that boils between 125 and 140 °C. Isoamyl alcohol can also be synthesized by condensation of isobutene and formaldehyde, which produces isoprenol, followed by hydrogenation. Isoamyl acetate is also produced synthetically by the rectification of amyl acetate. The Fischer esterification reaction was first described by Emil Fischer and Arthur Speier in 1895.
- Формула
- C₇H₁₄O₂ (isoamyl acetate, MW 130.18 g/mol)
- CAS
- 123-92-2 (isoamyl acetate)
- Ботанічна назва
- Musa sapientum
- Зовнішній вигляд
- colorless to pale yellow liquid
- Сила запаху
- Дуже сильна
- Синоніми
- banana oil, pear oil, isoamyl acetate, isopentyl acetate, 3-methylbutyl acetate
No IFRA Standard for the material itself (51st Amendment)
- Температура кипіння
- 142 °C
- Температура плавлення
- -78.5 °C
- Температура спалаху
- 25 °C (closed cup)
- Відносна густина
- 0.876 at 59 °F
- Показник заломлення
- 1.4000 at 20 °C
У парфумерії
Banana enhances the head of a perfume and adds banana or pear nuances, particularly in jasmine notes, though overdosing can make an accord excessively artificial. No PREMIEREPEAU fragrance uses a banana note.