Вишня

Cherry is a scent character shared by benzaldehyde, 4-methylbenzaldehyde and piperonal. Benzaldehyde has an odor similar to that of bitter almonds and cherry.
- Type
- Акорд
- Olfactive family
- Фруктові
Запах
Докладно
Цікавий факт
Piperonal was named heliotropin after the 'cherry pie' notes found in the heliotrope flower's fragrance, even though the chemical is not present in the flower's true aroma. Bitter almonds may yield 4-9 milligrams of hydrogen cyanide per almond. Prunus avium means 'bird cherry' in Latin, but in English 'bird cherry' refers to Prunus padus.
Отримання й хімія
Спосіб отримання
Bitter almonds contain the enzyme emulsin, which in the presence of water acts on amygdalin and prunasin, yielding glucose, cyanide and the essential oil of bitter almonds, which is nearly pure benzaldehyde. Piperonal can be prepared by the oxidative cleavage of isosafrole or by using a multistep sequence from catechol or 1,2-methylenedioxybenzene. 4-Methylbenzaldehyde may be prepared from the Friedel-Crafts formylation of toluene with carbon monoxide and hydrogen chloride under Gattermann-Koch conditions. Anisaldehyde is prepared commercially by oxidation of 4-methoxytoluene using manganese dioxide to convert a methyl group to the aldehyde group.
- Формула
- C₇H₆O (benzaldehyde)
- CAS
- 100-52-7 (Benzaldehyde)
- Ботанічна назва
- Prunus avium (sweet) Prunus cerasus (sour)
- Зовнішній вигляд
- Colorless liquid (benzaldehyde)
Restricted — IFRA Standard « Benzaldehyde » (Amendment 49)
- Температура кипіння
- 178.1 °C (benzaldehyde)
- Температура спалаху
- 64 °C (benzaldehyde)
- Показник заломлення
- 1.5456 (benzaldehyde)
У парфумерії
Piperonal is commonly used to add vanilla or almond nuances, generally imparting balsamic, powdery, and floral aspects to a scent's character. p-Tolualdehyde is used in the flavoring and fragrance industry because of its cherry and almond flavor and aroma. In perfumery, 4-anisaldehyde is particularly used in hawthorn, lilac, and cherry blossom accords because of its good tenacity. Bitter almond oil, containing benzaldehyde, is used as a food flavouring and in perfume.