Florol

СинтетичнийКВІТИквітковий · конвалія · цитрусовий
Верхні нотиПіраміда
3/5Сила
24годСтійкість
—Походження
Зразок
F
Верхні ноти
Визначення

Florol is a synthetic molecule, tetrahydro-4-methyl-2-(2-methylpropyl)-2H-pyran-4-ol. Its odour is a fresh, soft and natural floral note reminiscent of muguet.

КВІТКОВИЙ ЦИТРУСОВИЙ СВІЖИЙ
Florol, Florosa, Floral pyranol, Pyranol
Type
Складник
Olfactive family
Квіткові
Source
synthetic molecule
Chemical class
tetrahydropyran-4-ol
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
3/5Сила
Середня
інтенсивність запаху
Стійкість на блотері
24годин
1 год6 год24 год3 дн.7 дн.400 год
за 100 %

Запах

A description at 100 % lists fresh, clean, soft, natural, floral, muguet and linalool. Its technical descriptors are muguet and ozone. Another description gives fresh, floral (muguet, rosy), with a lightly earthy note. Florosa, a trade name of the same molecule, is described as floral, muguet and sweet, with a creamy floral muguet note.

Докладно

What it is

Florol is one of several trade names of a synthetic molecule, tetrahydro-4-methyl-2-(2-methylpropyl)-2H-pyran-4-ol. The same molecule also carries the trade names Florosa and Pyranol. Another of its names is 4-hydroxy-4-methyl-2-isobutyltetrahydropyran. Its molecular formula is C₁₀H₂₀O₂ and its molecular weight is 172.26. Its EC number is 405-040-6.

Chemistry

The material consists of a cis/trans-isomer mixture. The proportion of the more valuable cis-isomer can be increased by using dilute sulfuric acid as catalyst. Its water solubility is 23 g/L at 23 °C.

Muguet scent

No natural aromatic extract can be produced from lily-of-the-valley, so its scent must be recreated synthetically. Hydroxycitronellal was originally used to achieve this in one perfume, but the European Chemicals Agency now considers it a skin sensitiser and its use has been restricted.

Regulatory status

The molecule is TSCA listed and its REACH registration is active.

Explore all seven extraits in the Discovery Set.

—

Related: Arum Lily · Biomuguet · Calla Lily · Crinum Lily · Daylily · Fire Lily · Florhydral · Hydroxycitronellal

Отримання й хімія

Спосіб отримання

Florol is a synthetic molecule made by chemical synthesis. Cyclocondensation of 3-methyl-3-buten-1-ol with 3-methylbutanal on silica gel and alumina, without solvent, is proposed for its synthesis. In one preparation, an acetal was stirred with 5% phosphoric acid at 60 °C for 6 hours, and the reaction was stopped when the acetal content fell below 1%. The material was washed with 5% sodium hydroxide solution until the aqueous phase was weakly alkaline, then distilled, giving 2-isobutyl-4-hydroxy-4-methyltetrahydropyran with a GC content of 97% and a yield of 82%.

Формула
C₁₀H₂₀O₂
CAS
63500-71-0
Зовнішній вигляд
Colorless to pale yellow liquid
Сила запаху
Середня
Стійкість
24 hour(s) at 100.00 %
Синоніми
Florol, Florosa, Floral pyranol, Pyranol
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
225.00 °C. @ 760.00 mm Hg
Температура спалаху
100 °C / 212 °F
Відносна густина
0.94800 to 0.95500 @ 20.00 °C.
Показник заломлення
1.45600 to 1.46000 @ 20.00 °C.

У парфумерії

Florol can be used in almost all perfume types, where it gives elegant floral diffusion without changing the character of the fragrance. It is a very stable and substantive building block that can also replace less stable floral aldehydes. In fine fragrance it is listed as a top and heart note. It is stable in perfumes, face creams, talcum powders and other daily chemical products. Its recommended applications include shampoo, shower gel, soap, detergent and softener.

Роль у формулі
01піднесення верхніх нот
02свіжість
03модифікатор
Форми випуску
синтетична речовина

Див. також

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