AMBROX® SUPER

СинтетичнийМУСКУСИ Й АМБРОВІ АКОРДИдеревний · теплий · амбровий
Базові нотиПіраміда
4/5Сила
—Стійкість
—Походження

Редакційна приміткаМи не маємо жодних прав на цей матеріал, його назву чи торговельну марку. Ця стаття глосарію є незалежною редакційною журналістикою й опублікована на підставі свободи вираження поглядів.

Зразок
AMBROX® SUPER як парфумерна сировина
Базові ноти
Визначення

Ambrox Super is a synthetic amber aroma chemical based on ambroxide. It has a dry ambery odor with woody, musky and mineral facets.

ДЕРЕВНИЙ СОЛОДКИЙ ПУДРОВИЙ АМБРОВИЙ ТЕПЛИЙ ВЕРШКОВИЙ
ambroxide, ambroxan, (-)-ambroxide, ambroxene
Type
Складник
Olfactive family
Деревні
Chemical class
Terpenoid
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
4/5Сила
Висока
інтенсивність запаху

Запах

The odor of Ambrox Super is an extremely powerful and elegant amber with a musky, woody tonality. The aroma of ambroxide is described as ambergris, sweet, labdanum, dry, woody, pine, cedar, green, and seedy. Ambroxide has a scent with woody, musky and slightly salty nuances. The smell of (-)-ambroxide is ambery and woody, reminiscent of tobacco and clary sage.

Докладно

Ambrox Super is not natural ambergris and contains no whale-derived material.

Ambroxide is a naturally occurring terpenoid and one of the key constituents responsible for the odor of ambergris. Ambergris is a solid, waxy substance produced in the digestive system of sperm whales. Breakdown of the relatively scentless ambrein through oxidation produces ambroxide and ambrinol, the main odour components of ambergris. Ambroxide has the formula C₁₆H₂₈O and a molecular weight of 236.39.

Sclareol is a bicyclic diterpene alcohol. Sclareol is found in Salvia sclarea, from which it derives its name. Sclareol is the most common starting material for manufacturing ambroxide. Sclareol is extracted by steam distillation of fresh flowers, then purified by further extraction using an organic solvent.

Small amounts (< 0.01 ppm) of ambroxide are used as a flavoring in food.

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Related: Almond Tree · Amburana Wood · Amyris · Blonde Woods · Caoutchouc · Cashalox · Cashmir Wood · Cetonal

Цікавий факт

Ambergris occurs in only about one in a hundred sperm whales. The yearly use of (-)-ambroxide as a substitute for ambergris is estimated at more than 100 t.

Отримання й хімія

Спосіб отримання

Two partial bioproduction routes to ambroxide have been developed, using sclareol and (E,E)-homofarnesol as key intermediates; de novo biosynthesis of ambroxide has not yet been accomplished. Ambroxide in general is synthesized from sclareol, a component of the essential oil of clary sage. Sclareol is oxidatively degraded to a lactone, which is hydrogenated to the corresponding diol. The resulting compound is dehydrated to form ambroxide. A newer patented method uses homofarnesol as the raw material. This process was stated to require 100 times less agricultural surface than the traditional method from clary sage. In the homofarnesol route, an enzyme cyclizes the C16 terpene (E,E)-homofarnesol to (-)-ambroxide in a single step.

Формула
C₁₆H₂₈O
CAS
6790-58-5
Зовнішній вигляд
White crystals
Сила запаху
Висока
Синоніми
ambroxide, ambroxan, (-)-ambroxide, ambroxene
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
120-121 °C @ 1.40 mm Hg
Температура плавлення
70-77 °C
Температура спалаху
322 °F TCC (161.11 °C)
Показник заломлення
1.48 (nD)

У парфумерії

The most prominent use of ambroxide is in fine fragrance, where it serves simultaneously as a base note and a fixative. Ambroxide is used in perfumery for creating ambergris notes. Ambroxide clings to skin, fabric, and hard surfaces and persists for many hours, which is the basis of its role as a fixative. Ambrox Super is highly diffusive and brings a unique ambery effect from top notes to dry down. It blends well with moss and woody notes.

Роль у формулі
01фіксатор
02фірмова нота
03сполучний компонент
04формувач об’єму
Форми випуску
стандартна форма

Див. також

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