Абсолют кастореуму

НатуральнийНАТУРАЛЬНІ Й СИНТЕТИЧНІ, ПОПУЛЯРНІ Й НЕЗВИЧНІтваринний · шкіряний · теплий
Ноти серцяПіраміда
—Сила
—Стійкість
—Походження
Зразок
Абсолют кастореуму як парфумерна сировина
Ноти серця
Castor canadensis / Castor fiber
Визначення

Castoreum is a yellowish exudate from the castor sacs of mature beavers. Its odour is leathery, animalic and smoky.

Animalique
93
Cuiré
87
Fumé
76
Résineux
62
Castoreum extract, castoreum resinoid, castoreum tincture
Type
Складник
Olfactive family
Амброві й мускусні
Source
animal-derived
Chemical class
complex natural mixture
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти

Запах

Castoreum has a warm, animal-sweet odour, becoming more pleasant on dilution. Dilute castoreum, for example as a tincture in ethanol, smells pleasantly of birch tar and musk and is slightly fruity. It evokes notes of fur, ink, plum, black olives and dried fruits. Its odour is also described as animal, ink, leathery and phenolic.

Молекула: виробники й варіанти

Докладно

Beavers use castoreum in combination with urine to scent mark their territory. Both beaver sexes have a pair of castor sacs and a pair of anal glands, located in two cavities under the skin between the pelvis and the base of the tail. Beavers deposit castoreum on piles of debris and mud called scent mounds.

Source animals

The two living beaver species are the North American beaver (Castor canadensis) and the Eurasian beaver (Castor fiber). The North American beaver is native to North America. The Eurasian beaver is widespread across Eurasia.

Composition

At least 24 compounds are known constituents of beaver castoreum. Several of these have pheromonal activity; the strongest are the phenols 4-ethylphenol and catechol and the ketones acetophenone and 3-hydroxyacetophenone. Castoreum also contains nupharamine alkaloids, castoramine and cis-cyclohexane-1,2-diol. It contains castorin (0.33 to 2.5%) and volatile oil (1 to 2%), together with benzoic acid, salicylic acid, cinnamic acid and phenols. A minor component, 5-(3'-furyl)-8-methylindolizidine, makes up less than 0.0002% of castoreum.

The pouches

Canadian pouches are wrinkled, pear-shaped, almost flat, from 6 to 15 cm long and 4 to 8 cm wide. Siberian pouches are ovoid and smooth, slightly larger in size, but valued less commercially. Castoreum is a by-product of the fur industry. The fresh pouch contains a yellowish, butter-like mass. When the pouches are dried in the air or over a wood fire, the contents turn dark brown and become resinous.

Food use

In the United States, the Food and Drug Administration classes castoreum extract as a generally recognized as safe food additive.

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Related: Aldambre · Ambrarome · Ambrein · Ambreine · Ambrettolide · Ambronova · Ammonia · Animal Notes

Цікавий факт

The intense, leathery odour of castoreum from Siberian beavers is caused largely by phenolic compounds, which the beavers take in with their food and excrete into their abdominal pouches. In Sweden, castoreum has traditionally flavoured a kind of snaps called Bäverhojt.

Отримання й хімія

Спосіб отримання

Castoreum is removed from the animal during the skinning period and is dried in the sun or sometimes over burning wood. It is extracted with alcohol from the dried and crushed castor sacs. The dried beaver castor sacs are generally aged for two or more years to mellow. Hot alcohol extraction gives a yield of about 75 to 80%. This extract is not a true absolute and it is not clearly soluble in cold alcohol. Resinoids are prepared by extracting dried, comminuted pouches with suitable solvents. A commercial castoreum absolute is made by extraction using volatile solvents followed by a purification in alcohol. Today, there are special beaver farms where the beavers rub their secretions off onto special collection containers.

Формула
Complex natural mixture (key constituents: castoramine; 4-ethylphenol; catechol; acetophenone)
CAS
8023-83-4
Ботанічна назва
Castor canadensis / Castor fiber
Зовнішній вигляд
dark-brown, soft, unctuous mass
Синоніми
Castoreum extract, castoreum resinoid, castoreum tincture
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура спалаху
> 100 °C

У парфумерії

In perfumery, the term castoreum refers to the resinoid extract made from the dried beaver castor tinctured with alcohol. Castoreum is largely used for its note suggesting leather, typically compounded with other ingredients covering top, middle and base notes. It was used mainly in fine fragrances for its characteristic, long-lasting odour, particularly for delicate leather nuances. It is used as a tincture in some perfumes. Historically, compounds isolated from castoreum were used in strawberry and raspberry flavourings and vanilla substitutes. At present, however, the annual industry consumption is very low, around 100 kilograms. Castoreum was also considered as an ingredient for the flavour and odour of cigarettes.

Роль у формулі
01модифікатор
02фірмова нота
03фіксатор
04тепло
Форми випуску
абсолют синтетична речовина

Див. також

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