Aldambre

СинтетичнийПАХУЧІ РЕЧОВИНИамбровий · деревний · металічний
Ноти серцяПіраміда
3/5Сила
—Стійкість
—Походження
Зразок
Aldambre як парфумерна сировина
Ноти серця
Визначення

Aldambre is an aroma chemical whose IUPAC name is oxacyclododecan-2-one. Its odour is dry and woody-amber, with a hot metallic facet.

ДЕРЕВНИЙ АМБРОВИЙ СУХИЙ МЕТАЛІЧНИЙ МУСКУСНИЙ МІНЕРАЛЬНИЙ
Undecanolide, omega-undecalactone, 11-hydroxyundecanoic acid lactone
Type
Складник
Olfactive family
Амброві й мускусні
Source
Aroma chemical
Chemical class
Lactone
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
3/5Сила
Середня
інтенсивність запаху

Запах

Aldambre opens with a dry woody-amber character that feels clean, without dustiness or heaviness. A distinctive hot iron facet emerges quickly and adds a metallic edge. Soft musky undertones are present, and the overall effect remains warm without becoming cloying or animalic. The odour is reminiscent of a steam iron pressing clean linen, combined with sun-bleached driftwood and heated granite stones.

Докладно

Aldambre belongs to the amber odour family. Its INCI name is 11-hydroxyundecanoic acid lactone, and its IUPAC name is oxacyclododecan-2-one.

Lactones are cyclic carboxylic esters derived from hydroxycarboxylic acids. Oxacyclododecan-2-one is a 12-membered lactone and a macrocyclic ester. Macrocyclic lactones are known as macrolactones.

Macrocyclic lactones such as cyclopentadecanolide have odours similar to macrocyclic ketones of animal origin, muscone and civetone. Macrocyclic musk compounds form one of the three major classes of synthetic musks. Some plants, such as Angelica archangelica and Abelmoschus moschatus, produce musky-smelling macrocyclic lactone compounds. Oxacyclododecan-2-one may be used in the preparation of 11-hydroxyundecanoic acid.

Explore all seven extraits in the Discovery Set.

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Related: Ambrarome · Ambrein · Ambreine · Ambrettolide · Ambronova · Ammonia · Animal Notes · Beeswax

Цікавий факт

The anionic ring-opening polymerization of oxacyclododecan-2-one has been reported and compared with that of ε-caprolactone.

Отримання й хімія

Спосіб отримання

Lactones are formed by lactonization, the intramolecular esterification of the corresponding hydroxycarboxylic acid. Methods used for lactones include Yamaguchi esterification, Shiina macrolactonization and Corey-Nicolaou macrolactonization.

Формула
C₁₁H₂₀O₂
CAS
1725-03-7
Зовнішній вигляд
Liquid
Сила запаху
Moderate (4/10)
Синоніми
Undecanolide, omega-undecalactone, 11-hydroxyundecanoic acid lactone
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
124–126 °C @ 13 mmHg
Температура плавлення
2–3 °C
Температура спалаху
> 230 °F
Показник заломлення
n20/D 1.47

У парфумерії

Aldambre is used to abstract woody bases and to create contemporary mineral effects. Added at 0.5-2%, it strips earthiness from vetiver and patchouli. It can be combined with salicylates for hot stone accords or with Ambroxan to amplify mineral facets. It creates mineral accords and adds metallic lift to woods. At higher doses, it becomes a statement material for conceptual fragrances. It is described as a heart-note musk that bridges top and base. It can be used to modernise aldehydic florals.

Роль у формулі
01модифікатор
02фірмова нота
03сполучний компонент
Форми випуску
стандартна форма

Див. також

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