Копал

НатуральнийСМОЛИ Й БАЛЬЗАМИбальзамічний · теплий · насичений
Базові нотиПіраміда
—Сила
—Стійкість
4Походження
Зразок
Копал як парфумерна сировина
Базові ноти
Protium copal, Bursera spp., Hymenaea verrucosa
Визначення

Copal is a tree resin, particularly the aromatic resins from the copal tree Protium copal, used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. The resins of the Bursera species of the copal section have a very characteristic aromatic smell of pine and lemon.

ЦИТРУСОВИЙ СОЛОДКИЙ БАЛЬЗАМІЧНИЙ ПУДРОВИЙ АМБРОВИЙ ТЕПЛИЙ СВІЖИЙ СМОЛИСТИЙ
Copalli, subfossilized tree sap
Type
Складник
Olfactive family
Смолисті
Source
resin
Chemical class
triterpene and diterpene resin
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
Країни-виробники
Мексика Центральна Америка Східна Африка Мадагаскар

Запах

A copal statuette found in excavations beside the Templo Mayor site still gives off a sweet, eucalyptus-like aroma more than 500 years later. The burning resin sweats and bubbles and then becomes a heavy sweet smoke.

Докладно

What copal is

Copal is an immature recent resin, unlike amber, which is fossilized, hardened resin. More generally, the name covers resinous substances at a stage of polymerization and hardening between gummier resins and amber. Partly mineralized copal is known as copaline. In its natural condition, copal can be told from old amber by its lighter citrine colour and by a surface that turns tacky with a drop of acetone or chloroform. The word copal comes from the Nahuatl copalli, meaning incense.

Sources

Protium copal, commonly known as the copal tree, is a species of tree endemic to Mexico and Central America. It is found in wet tropical forests, preferring heavy shade. The genus Bursera has around 100 species throughout the American continent, of which 80 are distributed in Mexico. Bursera bipinnata is commonly known as copal chino and is considered a source of high-grade copal resin used in ceremonies and offerings. Copal resin from Hymenaea verrucosa, a member of Fabaceae, is found in East Africa and is used in incense. The sap of Hymenaea courbaril, called animé, is similar to copal in its nature and appearance. Subfossil copal is well known from New Zealand (as kauri gum from Agathis australis), Japan, the Dominican Republic, Colombia and Madagascar. It often has inclusions and is sometimes sold as young amber.

Chemistry

The resins of Bursera species contain principally triterpenes with ursane, oleanane and lupane skeletons. In the resin of Bursera bipinnata, α-amyrin and 3-epilupeol represent more than 67.90 percent of the resin. Of 15 compounds identified by GC/MS in the total resin of Bursera bipinnata, four triterpenes accounted for 79.48 percent and seven monoterpenes for 12.69 percent. The chemical profile of B. bipinnata differs from that of other copal resins such as B. copallifera in the presence of a greater variety of triterpenes. Residues of copal resins in archaeological Aztec samples showed triterpenes, of which 3-epilupeol, 3-epi-α-amyrin and α-amyrone were the most abundant. The essential oil of a commercial copal resin identified as possibly Bursera bipinnata contained 14.52 percent α-copaene and 13.75 percent germacrene D. East African copal is a diterpenic resin containing ozic acid, an enantiomer of communic acid, which polymerises as soon as it is exuded from the tree and comes into contact with air and light.

Uses

Copal can be sold as a varnish or molded into figurines. Copal resins are also used for medicinal purposes, such as an anti-inflammatory poultice, to plug dental cavities and to treat pneumonia. A number of indigenous peoples of Mexico and Central America still use copal as an incense, during sweat lodge ceremonies and sacred mushroom ceremonies. Aztec priests are believed to have packed incense pots with coal, copal and other aromatic substances for use in ceremonies. More than 300 copal objects from the offerings of the Great Temple of Tenochtitlan were studied, and they fall into six formal groups: bars, spheres, conglomerates, bases of sacrificial knives, anthropomorphic figurines and miscellaneous fragments. The resin was brought to Tenochtitlan as crude feedstock and transformed there into such objects. Two types of copal are produced by the same tree: gum, stone or wild copal, and santa, white or penca copal.

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Related: Amberwood · Andiroba · Bakhoor · Balsamic Notes · Benzoin · Benzoin Resinoid · Benzyl Benzoate · Benzyl Salicylate

Цікавий факт

In pre-Hispanic times, 8000 packages of wild copal wrapped in maize leaves and 400 baskets of white copal in bars were paid as tribute every 80 days. At the Templo Mayor, a large statue of Tlaloc atop the sacred pyramid held a leather bag full of copal in its left hand.

Отримання й хімія

Спосіб отримання

White copal is obtained by making diagonal cuts in the trunk or branches, which makes the semiliquid milky sap of the tree flow; it accumulates in agave leaves. As the substance hardens, it takes the form of its container, resulting in bars of white copal. Copal gatherers cut the tree with a wooden mallet and a large metal knife and catch the resin that oozes from the branches with rope and maguey spikes. The production of animé, the resin of Hymenaea courbaril, may be encouraged by wounding the bark. In East Africa, subfossil copal is found one or two meters below living copal trees, from roots of trees that may have lived thousands of years earlier.

Формула
Complex natural mixture (key constituents: alpha-amyrin; 3-epilupeol; alpha-phellandrene; ozic acid)
CAS
9000-14-0
Ботанічна назва
Protium copal, Bursera spp., Hymenaea verrucosa
Синоніми
Copalli, subfossilized tree sap
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Відносна густина
1.06 (+0.04, -0.03)
Показник заломлення
1.540 (-0.010)

У парфумерії

Copal is a subfossil tree resin of tropical regions, long used as incense and for making varnish. The dried sap of Protium copal is commonly used as an incense, similar to frankincense. When burned, copal gives off a white smoke. The sap of Hymenaea courbaril, called animé, is used for incense, perfume and varnish. In Mexico and Central America many people still use copal as incense.

Роль у формулі
01пахощі
Форми випуску
сира смола бруски

Див. також

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