Етилванілін

Ethylvanillin is a synthetic vanilla flavouring agent and a homologue of vanillin. Its aroma is described as sweet, creamy, vanilla, caramellic and root beer.
- Type
- Складник
- Olfactive family
- Гурманські
- Source
- synthetic molecule
- Chemical class
- benzaldehyde, phenol, aromatic ether
Запах
Докладно
Цікавий факт
The harmony of a perfume of the 1920s was created when a perfumer poured a bottle of ethylvanillin into a bottle of a fragrance created in 1889. Reducing the benzaldehyde group of ethylvanillin to a methyl group gives a compound called Ultravanil, also named vanilla cresol.
Отримання й хімія
Спосіб отримання
Ethylvanillin is prepared from catechol, beginning with ethylation to give guaethol. The ether condenses with glyoxylic acid to give the corresponding mandelic acid derivative, which by oxidation and decarboxylation gives ethylvanillin. It may also be prepared synthetically by the same methods as vanillin, using guethol instead of guaiacol as the starting material. Guaethol can also be condensed with chloral to give 3-ethoxy-4-hydroxyphenyl trichloromethyl carbinol, which is boiled with an alcoholic solution of KOH or NaOH, acidified and extracted with chloroform to yield ethyl vanillin. Another route runs from safrole by isomerization to isosafrole and oxidation to piperonal, followed by breaking the methylene linkage of piperonal with alcoholic KOH.
- Формула
- C₉H₁₀O₃
- CAS
- 121-32-4
- Зовнішній вигляд
- white to off-white powder
- Синоніми
- Ethyl vanillin, 3-ethoxy-4-hydroxybenzaldehyde, Bourbonal, Ethovan, Vanillal, Ethylprotal
No IFRA Standard for the material itself (51st Amendment)
- Температура кипіння
- 285.00 to 294.00 °C. @ 760.00 mm Hg
- Температура плавлення
- 76.00 to 78.00 °C. @ 760.00 mm Hg
- Температура спалаху
- 145 °C (293 °F), closed cup
У парфумерії
Ethylvanillin is used in flavouring and perfumery. It is used in perfumes, cosmetics, air fresheners and pharmaceuticals, as well as in the food industry. As a flavorant, it is about three times as potent as vanillin and is used in the production of chocolate. It is used in ice cream, beverages and baked goods. It enhances fruity and chocolate odour impression. Its addition is self-limiting, as too high a level may impart an unpleasant flavour in the product. It is used in tobacco flavor formulations. Ethylvanillin is involved in the synthesis of methyl dilantilis.