Триетилцитрат

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Т
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Визначення

Triethyl citrate is an ester of citric acid and a colorless, odorless liquid. It is a solvent, diluent and fixative in perfumes.

БЕЗ ЗАПАХУ
TEC, ethyl citrate, citric acid ethyl ester, citric acid triethyl ester, E1505
Type
Складник
Olfactive family
Амброві й мускусні
Source
Esterification of citric acid and ethanol
Chemical class
Ester of citric acid
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти

Запах

Triethyl citrate is described as an odourless liquid, and as having little odour. One description gives a fruity odor.

Докладно

Triethyl citrate (TEC, CAS 77-93-0, C₁₂H₂₀O₇) is an ester of citric acid. It is a colorless, odorless liquid that is slightly soluble in water and miscible in ethanol and ether. Its taste is bitter. It is stable under recommended storage conditions.

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Uses

In foods, triethyl citrate is used as a flavouring agent, solvent and surface-active agent. It is a food additive (E number E1505) used to stabilize foams, especially as whipping aid for egg white. It is also used in pharmaceutical coatings and plastics, and as a plasticizer for polyvinyl chloride (PVC) and similar plastics. In cosmetics it acts as a plasticiser in nail lacquers and hair care products and helps dispersing pigments in colour cosmetics. In cream formulations it can act as an emollient that improves skin feel and dissolves UV filters. In deodorants it inhibits the enzymatic decomposition of sweat components and therefore prevents body odour. It has also been used as a pseudo-emulsifier in e-cigarette liquids, where it works essentially like lecithin but can be vaporised.

Names and structure

Triethyl citrate belongs to the family of tricarboxylic acids and derivatives.

Metabolism

Triethyl citrate is hydrolyzed in vivo to citric acid and ethanol.

Цікавий факт

In deodorants, triethyl citrate is hydrolysed enzymatically to ethanol and citric acid. The citric acid lowers the skin pH, which deactivates bacterial lipase enzymes. A tested deodorant formulation containing 5% triethyl citrate at a pH of 4.5 showed deodorising efficacy over 24 h.

Отримання й хімія

Спосіб отримання

One cosmetic grade of triethyl citrate is a 100% bio-based material produced by esterification of fermentative-based citric acid and ethanol.

Формула
C₁₂H₂₀O₇
CAS
77-93-0
Зовнішній вигляд
Colorless oily liquid
Синоніми
TEC, ethyl citrate, citric acid ethyl ester, citric acid triethyl ester, E1505
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
294 °C
Температура плавлення
-55 °C
Температура спалаху
155 °C (311 °F) - closed cup
Відносна густина
1.1369 g/cu cm at 20 °C
Показник заломлення
1.440-1.444

У парфумерії

Its solvent, diluent and fixative performance is why it is used in perfumes and fragrances. It serves as an auxiliary substance in perfume oils. Its INCI functions are deodorising, diluent, emollient, fixative, plasticiser and solvent.

Роль у формулі
01фіксатор
02сполучний компонент
Форми випуску
синтетична речовина

Див. також

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