Aldehid C-12 MNA

SintetičkaPOPULARNO I NEOBIČNOaldehidni · metalan · voštan
Gornje notePiramida
4/5Jačina
388hTrajnost
—Poreklo
Uzorak
Aldehid C-12 MNA kao sirovina za parfeme
Gornje note
Definicija

Aldehyde C-12 MNA is 2-methylundecanal, an organic compound used as a fragrance component in soaps, detergents and perfumes. It smells herbaceous, orange and ambergris-like.

ALDEHIDNI AMBRAST VOŠTAN METALAN CITRUSNI
2-Methylundecanal, Methylnonylacetaldehyde, MNA, Aldehyde C-12, Aldehyde M.N.A.
Type
Sirovina
Olfactive family
Ambrasti i mošusni
Source
synthetic molecule
Chemical class
aldehyde
Instrumenti
Piramida
GGornje note
SSrednje note
BBazne note
4/5Jačina
Visoka
jačina mirisa
Trajnost na mirisnoj traci
388sati · 16 dana
1 h6 h24 h3 d7 d400 h
pri 100 %

Miris

At 1.00 % in dipropylene glycol it reads as fresh, amber, aldehydic, moss, citrus, tuberose, metallic, waxy and coumarinic. Another description gives gassy, diffusive, metallic and waxy, with coumarin and citrus nuances. A third describes a dry amber-like herbaceous odor. Another gives aldehydic, dry, amber and warm. One description calls it very intensive and aldehydic, with nuances reminiscent of ambergris and incense. Soapy and slightly green and ozonic facets are also reported.

Detaljno

Identity

Aldehyde C-12 MNA is a name for 2-methylundecanal, an organic compound of formula C₁₂H₂₄O. It is found naturally in kumquat peel oil. It is a colorless or pale yellow liquid that is soluble in organic solvents such as ether and ethanol.

Chemistry

Hexyl cinnamaldehyde, isobutyraldehyde and lilial are related alkyl aldehydes. The (R) and (S) enantiomers can be synthesized with high enantiomeric purity using the SAMP/RAMP hydrazone method. It is soluble in fixed oils, alcohol and propylene glycol, and insoluble in glycerol.

Flavor and food use

At high dilution it has a flavor similar to honey and nuts. At 2.00 ppm its taste is waxy, fatty and metallic, with citrus nuances. It is used as a food additive. It also gives an interesting topnote to fruit flavors such as peach and apricot.

Explore all seven extraits in the Discovery Set.

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Related: Aldehyde C 10 Decanal · Aldehyde C 11 Undecylenic · Aldehydes · Citrus Japonica · Clementine · Hand Cream · Hivernal · Methyl Pamplemousse

Zanimljivosti

2-Methylundecanal contains one asymmetric carbon atom, and a professional perfumer found only a slight difference in odor quality and intensity between its enantiomers.

Dobijanje i hemija

Način dobijanja

Industry makes 2-methylundecanal by two main routes. In the first, methyl nonyl ketone reacts with an alkyl chloroacetate to give a glycidate, which then undergoes saponification followed by decarboxylation. In the second, undecanal reacts with formaldehyde in the presence of base to give 2-methyleneundecanal, which is then hydrogenated to 2-methylundecanal. The 2-methylundecanal is separated from the by-products by fractional distillation. The undecanal required is generated from 1-decene by hydroformylation.

Formula
C₁₂H₂₄O
CAS
110-41-8
Izgled
Colorless or pale yellow liquid
Jačina mirisa
Visok
Trajnost
388 hours at 100.00 %
Sinonimi
2-Methylundecanal, Methylnonylacetaldehyde, MNA, Aldehyde C-12, Aldehyde M.N.A.
Status prema standardima IFRA
Pogledajte napomenu

No IFRA Standard for the material itself (51st Amendment)

Fizička svojstva
Tačka ključanja
171.00 °C. @ 760.00 mm Hg
Tačka paljenja
200.00 °F. TCC ( 93.33 °C. )
Relativna gustina
0.82200 to 0.83000 @ 25.00 °C.
Indeks prelamanja
1.43000 to 1.43600 @ 20.00 °C.

U parfemima

It is a fragrance element in soaps and detergents and in perfume, where it gives conifer notes, fir in particular. It is also used in fantasy compositions. It serves as an amber note in topnote complexes. It blends particularly well with floral, woody, amber and tobacco accords. It has good fabric substantivity.

Uloga u formuli
01podizanje gornjih nota
02difuzija
03modifikator
Oblici na tržištu
sintetički

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