Глід

АкордКВІТИквітковий · фруктовий · зелений
Ноти серцяПіраміда
3/5Сила
—Стійкість
—Походження
Зразок
Глід як парфумерна сировина
Ноти серця
Crataegus
Фантазійний/концептуальний
Визначення

Hawthorn is the common name of Crataegus, a genus of shrubs and trees in the rose family Rosaceae. In perfumery, hawthorn accords use 4-anisaldehyde, which has a sweet, floral and strong aniseed odor.

КВІТКОВИЙ ЗЕЛЕНИЙ СОЛОДКИЙ ФРУКТОВИЙ ТРАВ’ЯНИЙ ТЕПЛИЙ СВІЖИЙ
Mayflower, quickthorn, thornapple, May-tree, whitethorn, hawberry
Type
Акорд
Olfactive family
Квіткові
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
3/5Сила
Середня
інтенсивність запаху

Запах

4-Anisaldehyde is described as having a hawthorn odor. Its odor is also described as sweet powdery, spicy creamy, fruity, vanilla and hay-like, and as coumarin, almond, anisic with berry nuances. In another description the odor resembles that of coumarin.

Докладно

The plant

Crataegus species are shrubs or small trees, mostly growing to 5-15 m (15-50 ft) tall, with small fruit and (usually) thorny branches. They are native to temperate regions of the Northern Hemisphere in Europe, Asia, North Africa and North America. The number of species depends on taxonomic interpretation, and a reasonable number is estimated to be 200.

Flowers are five-petalled and grow in flat-topped clusters and are most typically white, although they can also be pale pink or occasionally scarlet. The name "hawthorn" was originally applied to the species native to northern Europe, especially the common hawthorn C. monogyna. The flowers of C. monogyna are moderately fragrant.

Chemistry

4-Anisaldehyde, or p-anisaldehyde, is an organic compound whose molecule consists of a benzene ring with a formyl and a methoxy group. Forty-seven volatile compounds were identified in the extracts of the common hawthorn flowers. The principal constituents were spathulenol (22.76%), cis-pinocamphone (19.86%), E-caryophyllene (6.87%), 1.8-cineole (4.52%), caryophyllene oxide (4.17%), and isomenthone (3.17%).

Regulation

The IFRA Standard on p-methoxybenzaldehyde (Amendment 51) sets a maximum of 1.4 % in finished products of Category 4.

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Related: Abelia · Almond Blossom · Alpha Terpineol · Alstroemeria · Alumroot · Amarillys · Amazon Moonflower · Amethyst Flower

Цікавий факт

The hawthorn, species unspecified, is the state flower of Missouri. A Scots saying warns against shedding any clothes before the summer has fully arrived and the mayflowers (hawthorn blossoms) are in full bloom.

Отримання й хімія

Спосіб отримання

Anisaldehyde is prepared commercially by oxidation of 4-methoxytoluene (p-cresyl methyl ether) using manganese dioxide to convert a methyl group to the aldehyde group. It can also be produced by oxidation of anethole.

Формула
Anisaldehyde (C₈H₈O₂, p-methoxybenzaldehyde)
CAS
123-11-5 (anisaldehyde)
Ботанічна назва
Crataegus
Зовнішній вигляд
Colorless to pale yellow liquid (anisaldehyde)
Сила запаху
Середня
Синоніми
Mayflower, quickthorn, thornapple, May-tree, whitethorn, hawberry
Статус IFRA
Обмежено

Restricted — IFRA Standard « p-Methoxybenzaldehyde » (Amendment 51)

Фізичні властивості
Температура кипіння
248.00 to 249.00 °C @ 760.00 mm Hg
Температура спалаху
116 °C (241 °F), closed cup
Показник заломлення
1.5730 at 20 °C

У парфумерії

In perfumery, 4-anisaldehyde is particularly used in hawthorn, lilac, and cherry blossom accords because of its good tenacity. It is used as an intermediate in the synthesis of other compounds important in pharmaceuticals and perfumery.

Роль у формулі
01модифікатор
02фірмова нота
03сполучний компонент
04формувач об’єму
05свіжість
Форми випуску
синтетичний акорд фантазійна нота

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