Фіалка

Violet is a flower scent whose characteristic note is the combination of alpha-ionone and beta-ionone, which perfumery and flavouring use with other components to recreate it. The scent of violet flowers is distinctive, with only a few other flowers having a remotely similar odor.
- Type
- Складник
- Olfactive family
- Квіткові
- Source
- Viola odorata flowers and leaves; ionones are also synthesised
- Chemical class
- apocarotenoids (C13-norisoprenoids)
Запах
Теруар і походження
Докладно
Цікавий факт
A single-nucleotide polymorphism in the OR5A1 receptor causes very significant differences in the odor perception of beta-ionone, both in sensitivity and also in subjective quality. People who are homozygous AA are about 100 times less sensitive to beta-ionone and at higher concentrations perceive a pungent sour or vinegar odor instead.
Отримання й хімія
Спосіб отримання
Ionone can be synthesised from citral and acetone with calcium oxide as a basic heterogeneous catalyst, by an aldol condensation followed by a rearrangement reaction. The aldol condensation product eliminates water to form pseudoionone. Acid catalysis then opens a double bond to form a carbocation, which rearranges with ring closure. The synthesis of alpha-isomethyl ionone involves a cross-aldol condensation of citral with methyl ethyl ketone. A high temperature and strong alkali are used. At Tourrettes-sur-Loup, violet leaves are mown between the beginning of May and the end of July and delivered the same day to Grasse, where they are processed into perfumes.
- CAS
- 8024-08-6
- Ботанічна назва
- Viola odorata
- Зовнішній вигляд
- Violet flower absolute: greenish olive viscous liquid.
- Синоніми
- Sweet violet, wood violet, English violet, common violet, florist's violet, garden violet
No IFRA Standard for the material itself (51st Amendment)
- Температура кипіння
- 126 to 128 °C at 12 mmHg (beta-ionone)
- Температура плавлення
- -49 °C (beta-ionone)
У парфумерії
Beta-ionone is an important fragrance chemical used in perfumery. Alpha-isomethyl ionone is often used in the flavouring and cosmetic industries, for example in aftershave lotions, bath products, hair care products, moisturizers, perfumes, shampoos and skin care products. It is used in perfume fragrances such as amber, chypre, violet, mimosa, reseda, iris, orris and cyclamen. It is used as well in berries, woody notes, ylang-ylang, leather, orange, nut, pistachio, muscatel and tobacco fragrances. The percentage of alpha-isomethyl ionone used in perfumes ranges approximately from 0.1% to 11.9%, with an average of 1.1%. It is usually used in conjunction with hydroxycitronellal, woody notes, copaiba, N-methyl ionone, ionone or vetiver. Violet leaf absolute remains in use in modern perfumery. Viola odorata is grown for its scent and taste properties, which are used in perfumery and confectionery respectively.