Тютюн

НатуральнийМУСКУС, АМБРОВИЙ АКОРД, ТВАРИННІ ЗАПАХИтеплий · солодкий · шкіряний
Базові нотиПіраміда
4/5Сила
—Стійкість
5Походження
Зразок
Тютюн як парфумерна сировина
Базові ноти
Nicotiana tabacum L.
Визначення

Tobacco absolute is a natural extract of tobacco leaves, obtained with solvents and used in perfumery. It smells rich and warm, with a deep tobacco-like aroma.

ЗЕМЛИСТИЙ ДИМНИЙ СОЛОДКИЙ ШКІРЯНИЙ ТЕПЛИЙ
Tobacco absolute, tobacco leaf extract, Nicotiana tabacum extract
Type
Складник
Olfactive family
Ароматичні
Source
cured leaves (Nicotiana tabacum)
Chemical class
complex natural (absolute)
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
4/5Сила
Висока
інтенсивність запаху
Країни-виробники
Бразилія Китай Індія Сполучені Штати Зімбабве

Запах

The aroma is rich, warm and woody, reminiscent of fine pipe tobacco, with mossy, earthy, sweet (hay, molasses, dried fruit) and smooth leathery nuances. The main descriptors are tobacco, leather, sweet hay, mossy, damp earth, molasses, dried fruit, smoky and warm wood. The scent family is woody, ambery and leathery. It is very potent, and even trace amounts can significantly impact a composition.

Докладно

The leaves used for tobacco concrete and tobacco absolute come exclusively from the Oriental and cigar types. Nicotiana tabacum is an annual plant that grows 1 to 3 metres high and is native to tropical and subtropical America. Nicotine makes up 90 to 95% of the pyridine alkaloids of the plant, with nornicotine and anatabine at roughly 2.5% each. The main polyphenols of the leaf are rutin and chlorogenic acid.

From leaf to aroma

After harvest the leaf is cured, then aged to improve its flavour. During curing and aging the carotenoids of the leaf are slowly oxidised and degraded. This gives the leaf a sweet hay, tea, rose oil or fruity aromatic flavour. Four methods of curing are common: air curing, fire curing, flue curing and sun curing. Air-cured tobacco dries for six to eight weeks in a well-ventilated barn, sheltered from wind and sun. In fire curing, smoke from a low-burning fire on the barn floor permeates the leaves, which gives them a distinctive smoky aroma and flavour. Fire curing takes three to ten weeks and gives a tobacco low in sugar and high in nicotine. Flue-cured tobacco is kept in an enclosed barn heated by flues of hot air, without direct exposure to smoke, and the process takes about a week. Virginia tobacco that has been flue-cured is also called bright tobacco, because flue curing turns its leaves gold, orange or yellow. Sun-cured tobacco dries uncovered in the sun and is used in Greece, Turkey and other Mediterranean countries to produce oriental tobacco. Cured tobacco is tied into hands or made into bales, which are aged for one to three years to improve flavour and reduce bitterness. Cigarette blends generally use three major types of tobacco: Oriental (also known as aromatic, Turkish or Greek tobacco), flue-cured (Virginia bright) and Burley (light air-cured).

Aroma compounds

Megastigmatrienone is the key flavour compound in tobacco. It is a cyclohexenone and a carotenoid-derived aromatic compound. As Tabanone, it is manufactured as a perfume ingredient. Solanone is an unsaturated ketone with the formula C₁₃H₂₂O that is used as a fragrance. Solanone was discovered in 1967 and occurs naturally in tobacco leaves. Because extracting the natural product is expensive, solanone is now mostly manufactured synthetically. Solanone is also found in blackcurrant buds. Dihydroactinidiolide, a volatile terpene with the formula C₁₁H₁₆O₂, occurs naturally in tobacco. It has a sweet, tea-like odour and is used as a fragrance. The odour of β-damascone is described as tobacco, rose, apple, tea and fruity. In the essential oils of Bulgarian Virginia, Burley and Oriental tobaccos, the main carotenoid degradation products include α-ionone, dihydro-β-ionone and β-damascenone. Ionone and its derivatives were not identified in the concrete and resinoid made from Bulgarian tobaccos. They were not identified in the commercial-grade absolute either, apart from 3-oxo-α-ionol and 3-oxo-7,8-dihydro-α-ionol.

Flower concretes

Concretes can also be extracted from the flowers of Nicotiana tabacum. The flower concrete of Oriental-type tobacco yielded 3.2% and that of Virginia-type tobacco 5.2%. The Oriental-type flower concrete has a very strong green odour with fresh undertones, reminiscent of freshly cut hay. The Virginia-type flower concrete has a very strong green odour with slight floral and honey-like undertones.

Цікавий факт

Megastigmatrienone, a carotenoid-derived compound, produces spice notes associated with wine and is also a metabolite of Brewer's yeast. Dihydroactinidiolide is one of the three components of the pheromone by which workers of the red fire ant recognise their queen.

Отримання й хімія

Спосіб отримання

Tobacco absolute is obtained from cured and aged tobacco leaves by extraction with organic solvents. The solvents may be polar or non-polar, and the technologies are well established. The absolute is made from tobacco concrete by extraction with ethanol at low temperature. In the Bulgarian preparations studied, the resinoid was made by extracting the plant material with 95% ethanol at 70 °C and the concrete with petroleum ether at 30 °C, followed by complete removal of the solvents. More recently, tobacco absolute has also been obtained by supercritical CO2 extraction, for use in perfumery and as a tobacco flavour enhancer.

CAS
84961-66-0
Ботанічна назва
Nicotiana tabacum L.
Зовнішній вигляд
Dark brown, viscous liquid to semi-solid
Сила запаху
Висока
Синоніми
Tobacco absolute, tobacco leaf extract, Nicotiana tabacum extract
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
~355 °C at 101 325 Pa
Відносна густина
0.936 - 0.973 g/mL at 25 °C
Показник заломлення
n20/D 1.508

У парфумерії

Tobacco absolute is a base note in perfumery. Tobacco concrete and tobacco absolute are used in fine perfumery for "tabac", "dry" or "masculine" scented perfumes. Concretes from Nicotiana flowers are a possible new aromatic product for perfumery and cosmetics. Tobacco resinoid is used in casing or top flavouring of tobacco blends for cigarettes and other tobacco products. Megastigmatrienone is used as a flavour in tobacco products, and solanone enhances the fragrance of tobacco and is used as a cigarette additive.

Роль у формулі
01модифікатор
02фірмова нота
03сполучний компонент
Форми випуску
абсолют CO₂-екстракт резиноїд

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