β-пінен

Натуральний і синтетичнийЗЕЛЕНІ НОТИ, ТРАВИ Й ФУЖЕРНІ АКОРДИсосновий · деревний · зелений
Верхні нотиПіраміда
4/5Сила
—Стійкість
—Походження
Зразок
β-пінен як парфумерна сировина
Верхні ноти
N/A — found in Pinus pinaster and Humulus lupulus
Натуральний / синтетичний
Визначення

Beta-pinene is a monoterpene, an organic compound found in plants. It has a woody-green pine-like smell.

ДЕРЕВНИЙ ЗЕЛЕНИЙ СОСНОВИЙ СМОЛИСТИЙ
nopinene, pseudopinene, 2(10)-pinene, pin-2(10)-ene
Type
Складник
Olfactive family
Ароматичні
Source
turpentine
Chemical class
monoterpene
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
4/5Сила
Висока
інтенсивність запаху

Запах

The odour is characteristic of turpentine, with a dry, woody or resinous aroma. Other descriptions give a piney, turpentine-like odour and a terpene odour. A dry woody, resinous piney aroma is also reported.

Докладно

What it is

Beta-pinene is the less abundant of the two isomers of pinene, the other being alpha-pinene. Pinene is a collection of unsaturated bicyclic monoterpenes. Both isomers are chiral, and both contain a strained four-membered ring. Beta-pinene is a colorless liquid soluble in alcohol, but not water.

Where it occurs

Beta-pinene is one of the most abundant compounds released by forest trees. Many plants from many botanical families contain it. Turpentine is composed of terpenes, primarily the monoterpenes alpha-pinene and beta-pinene. Optically active and racemic beta-pinenes are present in turpentine oils. Cannabis contains alpha-pinene and beta-pinene. In bergamot oil, beta-pinene is one of the key monoterpenes, at 6%.

Chemistry

Both alpha-pinene and beta-pinene are produced from geranyl pyrophosphate. In the presence of strong bases, beta-pinene can be converted to alpha-pinene. If oxidized in air, the allylic products of the pinocarveol and myrtenol family prevail. Industrially, myrcene is made by pyrolysis of beta-pinene. Reaction with formaldehyde, a Prins reaction, converts beta-pinene to nopol.

Explore all seven extraits in the Discovery Set.

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Related: Alpha Pinene · Angelica · Angelica Root · Angelica Root Oil · Artemisia · Barrenwort · Beachheather · Behini Tree

Отримання й хімія

Спосіб отримання

The pinenes in turpentine are separated and purified by distillation. Nowadays, turpentine is rarely the product of distillation of pine resin, but is a byproduct of pulping. The kraft process gives a pinene-rich turpentine, whereas the sulfite process gives one rich in cymene. Crude sulfate turpentine is a by-product of the kraft process. Refiners of crude sulfate turpentine primarily separate the purified turpentine into its main components, alpha- and beta-pinene.

Формула
C₁₀H₁₆
CAS
127-91-3
Ботанічна назва
N/A — found in Pinus pinaster and Humulus lupulus
Зовнішній вигляд
Colorless liquid
Сила запаху
High, recommended to smell in a 10% solution or less
Синоніми
nopinene, pseudopinene, 2(10)-pinene, pin-2(10)-ene
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
165-167 °C
Температура плавлення
-61.54 °C
Температура спалаху
36 °C (97 °F)
Відносна густина
0.86
Показник заломлення
1.4768 at 25 °C

У парфумерії

Beta-pinene is used in the production of other aroma compounds. When nopol is acetylated, the result is nopyl acetate, which is used as fragrance material. Myrcene, which is made from beta-pinene, is rarely used directly in the perfumery industry. Instead, it is a precursor to many fragrances, such as menthol, citral, citronellol, citronellal, geraniol, nerol and linalool. 2-Pinanol, derived from pinene, gives linalool upon pyrolysis.

Роль у формулі
01піднесення верхніх нот
02свіжість
03модифікатор
Форми випуску
ізолят синтетична речовина

Див. також

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