What lunar dust is
Lunar dust is regolith finer than lunar soil, with grain sizes less than one millimeter. Almost half of moondust is silicon dioxide glass created by meteoroids hitting the moon. Moondust is also rich in iron, calcium and magnesium bound up in minerals such as olivine and pyroxene. Lunar regolith and crust are chemically reduced, rather than significantly oxidized like the Earth's crust. The dust is electrically charged and sticks to any surface with which it comes in contact.
The smell in the lunar lander
After every moonwalk, the Apollo astronauts tramped the dust back inside the lander. Moondust was incredibly clingy, sticking to boots, gloves and other exposed surfaces. Once their helmets and gloves were off, the astronauts could feel, smell and even taste the moon. Moondust and gunpowder are not the same thing. Modern smokeless gunpowder is a mixture of nitrocellulose and nitroglycerin, which are not found in lunar soil.
Possible explanations
Astronaut Don Pettit suggested that moondust meeting moist air in a lunar module gives a 'desert rain' effect and some lovely odors. Gary Lofgren of the Lunar Sample Laboratory suggested that the gases evaporating from the moondust might come from the solar wind. Harrison Schmitt suggested that the smell, and his reaction to it, could be a sign that moondust is chemically active. Lofgren also noted that oxygen would readily combine with the dangling chemical bonds of the moondust, a process called oxidation that is akin to burning. Oxidation of moondust might produce an aroma like burnt gunpowder, though it happens too slowly for smoke or flames.
Moondust on Earth
Moondust on Earth has no smell. The samples brought back by Apollo astronauts have been in contact with moist, oxygen-rich air, and any smelly chemical reactions or evaporations ended long ago. Astronauts took special containers to hold the samples in vacuum, but the jagged edges of the dust cut the seals and let oxygen and water vapor in.
Recreating the smell
A smell lab at Arizona State University would ideally create the scent of the Moon and have one of the remaining moonwalkers say how close it smells to being there. Creating a smell involves a process called solid phase microextraction. The smelly thing is put in a jar, and a filament is attached to capture the smell it emits. Machines then analyze the scent to work out which molecules give off a particular smell.
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