Персик

Натуральний і синтетичнийФРУКТИ, ОВОЧІ Й ГОРІХИфруктовий · солодкий · квітковий
Ноти серцяПіраміда
5/5Сила
—Стійкість
1Походження
Зразок
Персик як парфумерна сировина
Ноти серця
Prunus persica
Визначення

Peach is a fruit aroma whose basic character is shaped by lactones. γ-Undecalactone, a lactone of peach accords, has a rich, creamy peach-like aroma.

КВІТКОВИЙ СОЛОДКИЙ ФРУКТОВИЙ ТЕПЛИЙ
Type
Акорд
Olfactive family
Фруктові
Source
Synthetic lactones such as γ-undecalactone
Chemical class
Lactones (cyclic carboxylic esters)
Інструменти
Піраміда
ВВерхні ноти
СНоти серця
ББазові ноти
5/5Сила
Дуже висока
інтенсивність запаху
Країни-виробники
Китай

Запах

The aroma of γ-undecalactone carries fatty, lactonic undertones, soft nutty and tropical nuances, and apricot, coconut and vanilla facets. Its warm, oily depth and lack of aldehydic pungency distinguish it from sharper fruit esters. As a liquid, it has a strong fruity odour like peaches. In peach fruits, some terpenes such as linalool impart a sweet, floral and alcoholic note. γ-Octalactone confers a sweet herbaceous, coconut-like odour and taste.

Докладно

The peach (Prunus persica) is a deciduous tree that bears edible juicy fruits. It belongs to the genus Prunus, part of the rose family. Peaches are called stone fruits because of the hardness of the seed casing.

Around 100 compounds have been identified in the skin and flesh of peaches. Of these, about 30 determine the typical peach aroma. Among the compounds identified, C6 compounds, esters, benzaldehyde, linalool, C13 norisoprenoids and lactones were the most abundant. Lactones, above all γ- and δ-decalactone, have been reported to act in association with C6 aldehydes, aliphatic alcohols, esters, norisoprenoids, phenylpropanoids and terpenes. Nectarines usually contain C9 aldehydes, γ-decalactone and terpenes, peaches contain mostly C6–10 lactones, and flat peaches are dominated by benzaldehyde, γ-decalactone and δ-dodecalactone.

Lactones are cyclic carboxylic esters derived from hydroxycarboxylic acids by esterification. The Greek prefix gives the ring size: a γ-lactone has a five-membered ring and a δ-lactone a six-membered ring. γ-Decalactone, also called peach lactone, has the formula C₁₀H₁₈O₂ and an intense peach flavour.

Hexyl acetate, γ-decalactone and linalool were identified as key odour active compounds of peach. Their odour thresholds are low: 0.002 mg/L for hexyl acetate, 0.011 for γ-decalactone and 0.006 for linalool. Nectarines generate fewer volatiles than peaches, but have more fruity and floral aroma notes due to greater ester, linalool and terpinolene production.

In the peach, polyunsaturated fatty acids such as linoleic and linolenic acid are the main precursors of aroma-related volatiles, generated via the lipoxygenase pathway or β-oxidation.

—

Related: Acai Berry · Acerola · Aldehyde C 14 Peach · Apple · Apricot · Banana · Black Cherry · Blackberry

Цікавий факт

In China the peach is regarded as a symbol of longevity. In 2023 China produced 65% of the world total of peaches and nectarines. Among temperate fruits, only the apple and the pear are produced in larger amounts than the peach.

Отримання й хімія

Спосіб отримання

Lactones are formed by lactonization, the intramolecular esterification of the corresponding hydroxycarboxylic acids. γ-Lactones are so stable that 4-hydroxy acids spontaneously cyclize. A peach essential oil has been obtained by steam distillation followed by solvent separation.

Формула
Key odorants: γ-decalactone (C₁₀H₁₈O₂), γ-undecalactone (C₁₁H₂₀O₂), δ-decalactone, linalool
CAS
104-67-6 (gamma-undecalactone, key synthetic)
Ботанічна назва
Prunus persica
Зовнішній вигляд
Colorless to pale yellow liquid (γ-decalactone)
Сила запаху
Very high (γ-undecalactone)
Статус IFRA
Див. примітку

No IFRA Standard for the material itself (51st Amendment)

Фізичні властивості
Температура кипіння
281 °C (γ-decalactone); 297 °C (γ-undecalactone)
Відносна густина
0.942-0.945 (γ-undecalactone)
Показник заломлення
1.448-1.453 (γ-undecalactone)

У парфумерії

Lactones contribute significantly to the flavour of fruit and of dairy products, and are therefore used as flavours and fragrances. γ-Decalactone is particularly important in the formulation of peach, apricot and strawberry flavourants for drinks, food, personal care products, pharmaceutical drugs and household goods. Peach volatiles are also important for the food and fragrance industry, where they are used as flavouring agents. γ-Decalactone is a notable industrial product with a peach-like aroma.

Роль у формулі
01модифікатор
02фірмова нота
03компонент піднесення
04сполучний компонент
05формувач об’єму
06свіжість
Форми випуску
accord essential oil synthetic lactones

Див. також

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